MICHIGAN STATE UNIVERSITY Department of Chemistry

NEWS ARCHIVE

Year 2023

December 29, 2023
Publication in conjunction with MSU CHEMISTRY
Structure Guided Design of VANOL-imidodiphosphorimidate Catalysts for the Catalytic Enantioselective Bromo Spiroketalization Reaction A. Mohammadlou, A. Chakraborty, M. Maday, X. Yin, L. Zheng, H. Gholami, K. Ashtekar, R. Staples, B. Borhan, W. Wulff ACS Catal. , 2024, 14(1), 426-436..
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December 3, 2023
Publication in conjunction with University of Idaho.
Manipulating nitration and stabilization to achieve high energy. A.K. Chinnam, J. Singh, R.J. Staples, J.M. Shreeve Science Advances , 2023, 9(46) eadk3754 .
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November 28, 2023
Publication in conjunction with Dartmouth College
Ortho-Alkoxy-benzamide Directed Formation of a Single Crystalline Hydrogen-bonded Crosslinked Organic Framework and Its Boron Trifluoride Uptake and Catalysis." F. Li, E. Li, K. Samanta, Z. Zheng, L. Wu, A.D. Chen, O.K. Farha, R.J. Staples, J. Niu, K. Schmidt-Rohr, C. Ke Angew. Chem. Int. Ed. , 2023, e20311601.
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October 12, 2023
Publication in conjunction with Dartmouth College
Tripodal Organic cages with Unconventional CH---O Interactions for Perchlorate Remediation in Water J. Samanta, M. Tang, M. Zhang, R.P. Hughes, R.J. Staples, C. Ke J. Am. Chem. Soc. , 2023, 145(4), 21723-21728.
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September 15, 2023
Publication in conjunction with Dartmouth College
Influence of metal on coordination geometry and solution dynamics in complexes of cis-ethylenebis(diphenylphosphine oxide) and Ln(OTf)3 (Ln = La, Sm, Lu) X-ray crystal structures and NMR titration studies G.G. Sands, G. Ertle, J. Mugemana, R.J. Staples, J. E. Binder, S.M. Biros Polyhedron , 2023, 245,116659 .
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September 15, 2023
Publication in conjunction with Grand Valley State University
Crystal structure of a (carboxymethyl)tyriethylazanium bromide-2-(triethylazaniumyl) acetate (1/1) hydrogen-bonded dimer. F.M. Carlson, R.J. Staples, S.M. Biros ACTA E. , 2023, 79(9) 800-6803, .
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August 30, 2023
Publication in conjunction with University of Idaho
Energetic performance of trinitromethyl nitrotriazole (TNMNT) and its energetic salts S. Lal, R.J. Staples, J.M. Shreeve Chem. Comm. , 2023, 52, 12341-123461.
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August 24 , 2023
Publication in conjunction with University of Idaho
Trinitromethyl-trazolone (TNMTO): a highly dense oxidizer S. Lal, R.J. Staples, J.M. Shreeve Dalton Trans. , 2023, 52, 12341-12346.
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August 14, 2023
Publication in conjunction with MSU Engineering and Material Science
C-H···π Interactions disrupt Electrostatic interactions between non-aqueous electrolyte solubility S. Samaroo1, C. Hengesbach, C. Bruggeman, N.G.G. Carducci, L. Mtemeri, R.J. Staples, T. Guarr, D.P. Hickey1 Nature , 2023 15, 1365-1373.
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MSU News Release
August 9 , 2023
Publication in conjunction with University of Idaho
A Dihydrazone as a remarkably nitrogen-rich thermostable and insensitive energetic material J. Singh, R.J. Staples, J.M. Shreeve Org. Lett. , 2023, 25(32, 6082-6088.
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July 20, 2023
Publication in conjunction with University of Idaho
Design and Synthesis of High-Performance Planar Explosives and Solid Propellants with Tetrazole Moieties S. Lal, R.J. Staples, J.M. Shreeve Org. Lett., 2023, 25, 5100-5104.
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May 24, 2023
Publication in conjunction with MSU CHEMISTRY
Thiol and H2S-Mediated NO Generation from Nitrate at Copper(II) P. Ghosh, M. Stauffer, M.E. Ahmed, J.A. Bertke, R.J. Staples, T.H. Warren JACS , 2023, 145(22), 12007-12012.
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May25, 2023
Publication in conjunction with University of Idaho
FOX-7 derived nitramines: Novel propellants and oxidizers for solid rocket propulsion. S. Lal, R.J. Staples, J.M. Shreeve Chem. Eng. Journal, 2023, 468, 143737.
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January , 2023
Publication Of First protien Collected on New Synergy Diffractometer
A Crosslinked Ionic Organic Framework for Efficient Iodine and Iodide Remediation in Water. Maity, S., Bingham, C., Sheng, W., Ehyaei, N., Chakraborty, D., Tahmasebi-Nick, S., Kimmel, T.E., Vasileiou, C., Geiger, J.H., Borhan, B. Analysis , 2023, 148, 1085.
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March 21, 2023
Publication in conjunction with MSU CHEMISTRY
A rare isocyanide derived from an unprecedented neutral yttrium(ii) bis(amide) complex R. Jena, F. Benner, F. Delano (IV), D. Holmes, J. McCracken, S. Demir, A. Odom Chem. Science , 2023,14, 4257-4264.
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March 22, 2023
Publication in conjunction with Grand Valley State University
A mixed phosphine sulfide/selenide structure as an instructional example for how to evaluate the quality of a model S. Parkin. J. Cunningham, B. Rawls, J.E. Bender, R.J. Staples, S.M. Biros ACTA E , 2023, E79, 28-32.
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March 8, 2023
Publication in conjunction with Grand Valley State University
Crystal structure of tert-butyl 3,6-diiodocarbazole-9-carboxylate E.N. Sielaff, R.J. Staples, S.M. Biros ACTA E , 2023, E79, 345-348.
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February 27, 2023, 2023
Publication in conjunction with University of Idaho
Bisnitramide-Bridged N-Substituted Tetrazoles with Balanced Sensitivity and High Performance A.K. Chinnam, R.J. Staples, J.M. Shreeve Org. Lett., 2023, 25, 1481-1485 .
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February 22, 2023, 2023
Publication in conjunction with University of Idaho
Design and synthesis of phenylene-bridged isoxazole and tetrazole-1-ol based energetic materials of low sensitivity S. Lal, R.J. Staples, J.M. Shreeve Dalton Trans. , 2023, 52(11), 3449-3457.
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February 8, 2023
Publication in conjunction with University of Idaho
Increasing the limits of energy and safety in tetrazoles: dioximes as unusual precursors to very thermostable and insensitive energetic materials J. Singh, R.J. Staples, J.M. Shreeve J. Mater. Chem. A , 2023.
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January 30, 2023
Publication in conjunction with MSU Department of Chemistry
Guanidinate Rare-Earth Tetraphenylborate Complexes and Their Prospects in Single-Molecule Magnetism F. Delano IV, S. Demir Cryst. Growth Des. , 2023, 23, 5, 3134-3143.
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January 23, 2023
Publication in conjunction with MSU Department of Chemistry
Linear, Electron-Rich, Homoleptic Rare Earth Metallocene and Its Redox Activity E. Castellanos, S. Demir Inorg. Chem. , 2023, 62, 6, 2095-2104.
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January 19, 2023
Publication in conjunction with MSU Department of Chemistry
Molecular Switch Cobalt Redox Shuttle with a Tunable Hexadentate Ligand A.L. Raithel, W.E. Meador, T-Y Kim, R.J. Staples, J.H. Delcamp, T.W. Hamann J. Amer. Chem. Soc. , 2023, 145(2), 1367-1377.
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Year 2022

December 15, 2022
Publication in conjunction with Western New Englang University
Photoswitching Properties of 5-Methoxy-2-(2-phenyldiazenyl) Pyridine. J.T. Foy, N. Ta, J. Hoyt, R.J. Staples, C. Ehm, Chemistry Select , 2022, 7(47), e202204517.
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December 20, 2022
Publication in conjunction with University of Idaho, Chemistry Department
Balancing Energy and Stability of Nitroamino-1,2,4-Oxadiazoles through a Planar Bridge. J. Singh, Staples, Richard, J. J.M. Shreeve Organic Letters, 2022, 24(48), 8832-8836..
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December 1, 2022
New HIGH Pressure Synergy Diffractometer is operational in the CCR, Professor Weiwei Xie purchased athis system to perfrom Hign Pressure Crystallography here at MSU.
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November 24, 2022
Publication in conjunction with Dartmouth College
A Crosslinked Ionic Organic Framework for Efficient Iodine and Iodide Remediation in Water. M. Zhang, J Samanta, B.A. Atterberry, R.J. Staples, Richard, A.J. Rossini, C. Ke Angew Chem. Int. Ed. , 2022,61, e20221489.
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November 7 23, 2022
Publication in conjunction with University of Idaho, Chemistry Department
Effects of nitric acid concentration for nitration of fused [1,2,5]oxadiazolo[3,4-d]pyrimidine-5,7-diamine A.K. Chinnam, Y. Tang, R.J. Staples, Richard, J. J.M. Shreeve Dalton Trans., 2022, 51(47), 17987-17993.
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October 23, 2022
Publication in conjunction with University of Idaho, Chemistry Department
Highly Selective Nitroamino Isomerization Guided by Proton Transport Dynamics: Full-Nitroamino Imidazole[4,5-d]pyridazine Fused-Ring System Y. Wang, L. Hu, R.J. Staples, Richard, S. Pang, J. J.M. Shreeve Appl. Mater. Interfaces, 2022, 14(47), 52971-52978.
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October 7, 2022
Publication in conjunction with University of Idaho, Chemistry Department
FOX-7 based nitrogen rich green energetic salts: Synthesis, characterization, propulsive and detonation performance S. Lal, R.J. Staples, J.M. Shreeve Chem. Eng. J., 2023, 139600.
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October 4, 2022
Publication in conjunction with University of Idaho, Chemistry Department
Energetic Salts of Sensitive N,N′-(3,5-Dinitropyrazine-2,6-diyl)dinitramide Stabilized through Three-Dimensional Intermolecular Interactions J. Singh, A.K. Chinnam, R.J. Staples, J.M. Shreeve Inorganic Chemistry, 2022, 61(41), 1643-16500.
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October, 2022
Publication in conjunction with Grand Valley State University, Chemistry Department
Crystal structure of chlorido[diphenyl(thiophen-2-yl)phosphine-κP]gold(I) T. Neils, A. LaDuca, J.E. Bender, R.J. Staples, S.M. Biros Acta Cryst E., 2022, 78(10), 1044-11047.
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October, 17, 2022
Publication in conjunction with Dartmouth University, Chemistry Department
Construction of Highly Thermostable and Insensitive Three-Dimensional Energetic Salts Based on [1,2,5]Oxadiazolo[3,4-d]pyrimidine J. Samanta, R.W. Dorn, W. Zhang, X. Jiang, M. Zhang, R.J. Staples, A.J. Rosini, C. Ke. Organic letters, 2022, 8(10), 2678-2687.
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July 18, 2022
Publication in conjunction with Calvin College
Synthesis of Ester-Substituted Indolizines from 2-Propargyloxypyridines and 1,3-Dicarbonyls H. Bos, D. Dreher, C. Hartgernink, C. Colin, R.J. Staples, C. Anderson The Journal Of Organic Chemistry , 2022, 87(15), 10241-10249.
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July 11, 2022
Publication in conjunction with Univeristy of Idaho
Synthesis of a high-energy-density material through rapid replacement of crystal water of hydrates. J. Zhang, Y. Feng, Y. Bo, A.K. Chinnam, J. Singh , R.J. Staples, X. He, K. Wang, J. Zhang, J.M. Shreeve Chem , 2022, 8(1), 2678-2687.
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June 24, 2022
Publication in conjunction with MSU Department of Chemistry
Ligand-Field Spectroscopy of Co(III) Complexes and the Development of a Spectrochemical Series for Low-Spin d6 Charge-Transfer Chromophores J.T. Yarranton, J.K. McCusker J. Am. Chem. Soc. , 2022, 144(27), 12488-12500.
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June 23, 2022
Publication in conjunction with University of Idaho
Engineering bistetrazoles:(E)-5,5’-(ethene-1,2-diyl)bis(1H-tetrazol-1-ol) as a new planar high-energy-density material J. Singh , R.J. Staples, J.M. Shreeve Material advances , 2022, 3(14), 6062-6068.
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June, 6, 2022
Publication in conjunction with Grand Valley State University
Synthesis of diphenyl-(2-Thienyl)phosphine, its chalcogenide derivatives and a series of novel complexes of lanthanide nitrates and triflates. T. Luster, H.J. Van de Roovaart, K.J. Korman, G. G. Sands, K.M. Dunn, A. Spyker, R.J. Staples, S. M. Biros, J.E. Bender Dalton Tran. Front., 2022, 51, 9103-9115.
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May 18, 2022
Publication in conjunction with Dartmouth College
Asymmetric De Novo Synthesis of a Cucurbitane Triterpenoid: Total Synthesis of Octanorcucurbitacin B Bucknam, AR and Micalizio, GC J. Am. Chem. Soc. , 2022, 144(19), 5818-5829..
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May 10, 2022
Publication in conjunction with University of Idaho, Chemistry Department
Nitro-based and nitro-free tri-cationic azole salts: a unique class of energetic green tri-ionic salts obtained from the reaction with nitrogen-rich bases A.K. Chinnam, R.J. Staples, G. Zhao, J.M. Shreeve Materials Advances, 2022, 3(12), 5012-5018.
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April 16, 2022
Publication in conjunction with MSU Department of Chemistry
Investigation of phosphine donor properties to vanadium(V) nitrides L. Mo, H.I.Barr, A.L. Odom Results in Chemistry , 2022, 4, 100344.
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April , 2022
Publication in conjunction with MSU Department of Chemistry
Isolation of the elusive bisbenzimidazole Bbim(3-center dot) radical anion and its employment in a metal complex Benner, F and Demir, S Chemical Science , 2022, 13(20), 5818-5829..
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April 13, 2022
Publication in conjunction with University of Idaho, Chemistry Department
pH-Controlled forms of 1-amino-1-hydrazino-2,2-dinitroethylene (HFOX): selective reactivity of amine and hydrazinyl groups with aldehydes or ketones A.K. Chinnam, R.J. Staples, J.M. Shreeve Materials Advances , 2022, 3(10), 4289-4294.
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April 1, 2022
Publication in conjunction with University of Idaho, Chemistry Department
Bis(3-(trinitromethyl)-1H-1,2,4-triazol-5-yl)methanone: A mildly acidic high-performing energetic material A.K. Chinnam, J. Singh, R.J. Staples, J.M. Shreeve Chem. Eng. Journal, 2022, 433, 13352.
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March 1, 2022
Publication in conjunction with University of Idaho, Chemistry Department
Pyrazole bridges ensure highly stable and insensitive bistetrazoles J. Singeh, J.P. Hooper, J.M Shreeve Chem. Eng. Journal, 2022, 431 (part4), 133282.
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Feb 22, 2022
Publication in conjunction with University of Idaho, Chemistry Department
Functionalized planar aromatic rings as precursors to energetic N,N′-(4,6-dinitro-1,3-phenylene)dinitramide and its salts J. Singh, S. Sohan, R.J. Staples, J.M. Shreeve Materials Chemistry Frontiers, 2022, 6(7), 933-938.
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February 9, 2022
Publication in conjunction with MSU Department of Chemistry
Steric Shielding Effects Induced by Intramolecular C–H···O Hydrogen Bonding: Remote Borylation Directed by Bpin Groups J.R.M.Bastidas, A. Chhabra, Y. Feng,T.J. Oleskey, M.R. Smith III, and R.E. Maleczka Jr. ACS Catal. , 2022, 12(4), 2694-2705.
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January 18, 2022
Publication in conjunction with MSU Department of Chemistry
Heteroleptic Rare-Earth Tris(metallocenes) Containing a Dibenzocyclooctatetraene Dianion. E.R. Pugliese, F. Benner, E. Castellano, F. Delano IV, S. Demir Inorg. Chem., 2022, 61, 2444-2454.
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January 13, 2022
Publication in conjunction with Dartmouth University, Chemistry Department
An ultra-dynamic anion-cluster-based organic framework J. Samanta, R.W. Dorn, W. Zhang, X. Jiang, M. Zhang, R.J. Staples, A.J. Rosini, C. Ke. ACS Chem., 2022, 8(1), 253-267.
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Year 2021

January 21, 2022
Publication in conjunction with Department of Chemistry
Taming Salophen in Rare Earth Metallocene Chemistry. E. Castellano, F. Benner, S. Demir Inorg. Chem. Front., 2022, 9(7), 1325-1336.
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December 2, 2021
Publication in conjunction with Department of Chemistry
Organometallic Lanthanide Bismuth Cluster Single-Molecule Magnets. P. Zhang, F. Benner, N.F. Chilton, S. Demir Chem., 2021,8, 1-14.
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October 20, 2021
Publication in conjunction with Department of Chemistry
A Rare Earth Metallocene Containing a 2,2’-Azopyridyl Radical Anion. F. Delano IV, E. Castellano, J. McCracken, S. Demir Chem., 2021,12, 15219-15228. COVER
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November 17, 2021
Publication in conjunction with Forensic Science Program, School of Criminal Justice, MSU, Department of Chemistry
Optical and spectroscopic characterization of crystalline structures in cannabis extracts. O.R. Abraham, R.W. Smith J. Forensic Sci., 2021, 67(2), 483-493.
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December 28, 2021
Publication in conjunction with University of Idaho, Chemistry Department
Pushing the Limit of Nitro Groups on a Pyrazole Ring with Energy-Stability Balance. J. Singh, R.J. Staples, J.M. Shreeve Chem. Eng. J , 2021, 13(51), 61357-61364.
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December 7, 2021
Publication in conjunction with Dartmouth College, Department of Chemistry
An Ultra-dynamic anion-cluster-based organic framework. J. Samanta, R.W. Dorn, W. Zhang, X. Jiang, M. Zhang, R.J. Staples, A.J. Rosini, C. Ke. J. Chem, 2022, 8(1), 253-267.
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December 3, 2021
Publication in conjunction with Michigan State University, Chemistry Department
Probing Catalyst Function-Electronic Modulation of Chiral Polyborate Anionic Catalysts W.E.G. Osminski, Z. Lu, W. Zhao, A. Mohammadlou, E.C. Matthews, V.M. Canestraight, R.J. Staples, C.J. Allen, J.S. Hirshi, W.D. Wulff J. ORG. Chem., 2021, 86, 1762-1773.
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December 3, 2021
Publication in conjunction with University of Idaho, Chemistry Department
Bis(3-(trinitromethyl)-1H-1,2,4-triazol-5-yl)methanone: A mildly acidic high-performing energetic material. A.K. Chinnam, J. Singh, R.J. Staples, J.M. Shreeve Chem. Eng. J , 2022, 433, 133520.
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December 1, 2021
Publication in conjunction with University of Idaho, Chemistry Department
Nucleophilic Catalyzed Structural Binary Cleavage of a Fused [5,5]-bicyclic Compound. A.K. Chinnam, R.J. Staples, J.M. Shreeve Organic Let., 2021, 23, 9408-94112.
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November 21, 2021
Publication in conjunction with Kalamazoo College, Department of Chemistry
Hannah Hong , from Kalamazoo College presented her summer research at the Western Michigan Regional Undergraduate conference last weekend, including the crystal structure you solved for us. Talk was titled "Synthesis of Diacetylene Monomers for the Use of Cross-Reactive Polypeptoid Nanomaterials”. November 20, 2021.Blakely Tresca, Roger F. and Harriet G. Varney Assistant Professor
November 11, 2021
Publication in conjunction with University of Idaho, Chemistry Department
1,2-Bis(5-(trinitromethyl)-1,2,4-oxadiazol-3-yl)diazene: A Water Stable, High-Performing Green Oxidizer. A.K. Chinnam, R.J. Staples, J.M. Shreeve Dallton Trans., 2021, 50(46), 16929-16932.
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November 11, 2021
Publication in conjunction with University of Idaho, Chemistry Department
Pyrazole bridges ensure highly stable and insensitive bistetrazoles. J. Singeh, J.P. Hooper, J.M Shreeve Chem. Eng. J., 2022, 431(part4) 133282.
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November 8, 2021
Publication in conjunction with University of Idaho, Chemistry Department
Bridged and Fused Triazolic Energetic Frameworks with an Azo Building Block towards Thermally Stable and Applicable Propellant Ingredients. Q. Yu, F. Li, P. Yin,S-P, Pang, R.J. Staples, J.M. Shreeve J. Mater. Chem: Mater. Ener. And Sust, 2021, 9(41), 24903-2408.
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November 8, 2021
Publication in conjunction with University of Idaho, Chemistry Department
Assembling Nitrogen-rich, Thermally Stable, and Insensitive Energetic Materials by Polycyclization. A. Kumar, J. Singh, R.J. Staples, J.M. Shreeve Chem. Eng. J., 2022, 431(part3) 133235.
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October 3, 2021
Publication in conjunction with Dartmouth College, Chemistry Department
A Heteromeric Carboxylic Acid Based Single-Crystalline Crosslinked Organic Framework. R. Liang, J Samanta. B. Shao, M. Zhang, R.J. Staples, A.D. Chen, M. Tang, Y. Wu, I. Aprahamian, C. Ke Angewandtte Chemie, 2021, 60, 23176-23181.
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September 14, 2020
Publication in conjunction with University of Idaho, Chemistry Department
One Step Closer to an Ideal Insensitive Energetic Molecule: 3,5-diamino-6-hydroxy-2-oxide-4-nitropyrimidone and its Derivatives. J. Zhang, Y. Feng, Y. Bo, R.J. Staples,J Zhang, J.M. Shreeve J. Am. Chem. Soc., 2021, 143, 12665-12674.
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July 8, 2021
Publication in conjunction with Department of Chemistry
Silylcyclopropanes by Selective [1,4]-Wittig Rearrangement of 4-Silyl-5,6-dihydropyrans L.M. Mori-Quiroz, E.W. Maloba, R.E. Maleczka Jr. Organic Letters , 2021, 23(15), 5724-5728.
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July , 2021
Publication in conjunction with Department of Chemistry
Total Synthesis of Nortopstentin D via a Late-Stage Pinacol-like Rearrangement K.L. Keel, J.J. Tepe: Organ. Let., 2021, 23(14), 5368-5372.
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July 19, 2021
Publication in conjunction with Alabama A&M University, Department of Physics, Chemistry and Math
Synthesis, identification, density functional and Hirshfeld surface studies of 2,2’-disulfanediylbis(tetrahydro-4H-cyclopenta[d][1,3,2]dioxaphosphole-2-sulfide A.M. Mkadmh, Z.S. Safi, A.A. Elkhaldy, R.J. Staples, S. Kaya, G. Serdaroglu Journal of Computational Chemistry , 2021, 1-12.
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July 2, 2021
Publication in conjunction with Wayne State University, Department of Chemistry
Dual anticancer and antibacterial activities of bismuth compounds based of asymmetric [NN’O] ligands A.K. Chinnam, I.M. Marzano, D. Tomco, R.J. Staples, E.H. Lizarazo-Jaimes, D. A. Gomes, M. Bucciarelli-Rodriguez, W. Guerra, I.P.de Souzal, C.N. Verani, E.C. Pereira-Maia Journal of Inorganic Biochemistry , 2021, 222, 111522.
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May 20, 2021
Publication in conjunction with University of Idaho, Chemistry Department
Energetic Tricyclic Polynitropyrazole and Its Salts: Proton-Locking Effect of Guanidium Cations Y. Tang, W. Huang, A. Kumar, J. Singh, R.J. Staples, J.M. Shreeve Inorganic Chemistry, 2021, 60, 8339-8345.
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May 19, 2021
Publication in conjunction with University of Idaho, Chemistry Department
Selective synthesis of bis-(3-(3-(trifluoromethyl)-1H-1,2,4-triazol-5-yl)-4,4’-azo and azoxy furan derivatives A. Kumar, R.J. Staples, J.M. Shreeve J. Organic Chemistry., 2021, 86, 7781-7786.
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April 9, 2021
Publication in conjunction with Grand Valley State University, Department of Chemistry
Synthesis and Crystallographic Characterization of X-Substituted 2,4-Dinitrophenyl-4’-phenylbenzenesulfonates B.A. Stenfors, R.J. Staples, S.M. Biros, F.N. Ngassa Chemistry, 2021, 2(2), 591-599.
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May 5, 2021
Publication in conjunction with University of Idaho, Chemistry Department
Energetic compounds based on new fused triazolo[4,5]pyridazine ring: Nitroimino lights up energetic performance L. Hu, R.J. Staples, Shreeve Chem. Eng. J., 2021, 420, 129839.
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April 16, 2021
Publication in conjunction with Calvin University, Department of Chemistry and Biochemistry
Crystal structure of (µ-Oxoethenylidene)_tris(2-dicyclohexylphosphino-2,6-dimethoxy-1,1-biphenyl)-tri-gold(I) trifluoromethanesulfonylimide C.T. Hartgerink, R.J. Staples, C.E.A. Anderson Acta Cryst. , 2021, E77, 537-541.
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April 9, 2021
Publication in conjunction with University of Idaho, Chemistry Department
Taming nitroformate through encapsulation with nitrogen-rich hydrogen-bonded organic frameworks J. Zhang, Y.Feng, R.J. Staples, J. Zhang, J.M. Shreeve Nat. Communications, 2021, 12, 2146.
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February 22, 2021
Publication in conjunction with University of Idaho, Chemistry Department
Synthesis and energetic properties of trifluoromethyl-substituted 2-nitro-[1,2,4]triazole[1,5-a]pyrimidine derivatives A.K. Chinnam, R.J. Staples, J.M. Shreeve J. Florine Chemistry, 2021, 245, 109743.
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February, 4, 2021
Publication in conjunction with University of Idaho, Chemistry Department
One-step synthesis to an insensitive explosive: N,N”-bis(1H-tetrazol-5yl)methyl)nitramide (BTMNA) Y. Tang, K. Li, A.K. Chinnam, R.J. Staples, J.M. Shreeve Chem. Eng. Journal, 2021, 412, 128697.
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January, 25, 2021
Publication in conjunction with University of Idaho, Chemistry Department
Mono-N-oxidation of Heterocycle-Fused Pyrimidines. Y. Tang, K. Li, A. K. Chinnam, R. J. Staples, J. M. Shreeve Dalton trans., 2021, 50(6), 2143-2148.
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Year 2020

December 28, 2020 300th For Dr Richard J. Staples
Publication in conjunction with Michigan State University, Chemistry Department
Long-range Stereodirecting Participation across a Glycosidic Linkage om Glycosylation Reactions W. Yang, J. Zhang, C.-W. Yang, S. Ramadan, R.J. Staples, X. Huang OrgLett., 2021, 23(4), 11553-1156.
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December 22, 2020
Publication in conjunction with University of Idaho, Chemistry Department
Hydrogen bond system generated by nitroamino rearrangement:new character for designing next generation energetic materials. L. Hu, R. J. Staples, J. M. Shreeve ChemComm., 2021, 57(5), 603-606.
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December 16, 2020
Publication in conjunction with University of Idaho, Chemistry Department
HFOX ‒ 1-Amino-1-hydrazino-2,2-dinitroethylene as a precursor to trifluoromethyl, dinitro or trinitro-based energetic 1,2,4-triazoles A.K. Chinnanni, R.J. Staples, J.M. Shreeve Org. Lett. , 2021, 23, 76-80.
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December 9, 2020
Publication in conjunction with Michigan State University, Chemistry Department
Ritter-Enabled Catalytic Asymmetric Chloroamidation of Olefins D. C. Steigerwald, B. Soltanzadeh, A. Sarkar, C. C. Morgenstern, R.J. Staples, B. Borhan Chemical Science, 2021, 12(5), 1834-1842.
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December 1, 2020
Publication in conjunction with University of Idaho, Chemistry Department
Very thermostable energetic materials based on a fused-triazole. Y. Tang, Z. An, A. K. Chinnam, R. J. Staples, J. M. Shreeve New J. Chem , 2021, 45, 85-91.
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November 24, 2020
Publication in conjunction with University of Idaho, Chemistry Department
A Duo and a Trio of Triazoles as Very Thermostable and Insensitive Energetic Materials. Y. Tang, Z. Yin, A.K. Chinnanni, R.J. Staples, J.M. Shreeve Inorg. Chem., 2020, 59(23), 1776-1774.
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November 12, 2020
Publication in conjunction with University of Idaho, Chemistry Department
An Azo-bridged Triazole Derived from Tetrazine. Q. Yu, R.J. Staples, J.M. Shreeve Z. Anorg. Allg. Chem., 2020, 646(22), 1799-17804.
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October 20, 2020
X-ray Diffraction Course to be offered MSU Chemistry Depeartment Spring 2021
Using X-ray Diffraction to Provide Answers; Theory and Practice
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October 8, 2020
Publication in conjunction with School of Chemistry and Physics, University of KwaZulu-Natal, South Africa
Silver(I) Bis(phosphanylamino)naphthalene Complexes: Synthesis, Structures, and Density Functional Theory (DFT) Calculations. F.S.W. Potwana, M.N. Pillay, R.J.Staples, P.Singh, W.v. Zyl Inorganica Chimica Acta, 2021, 515, 12004.
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October 6, 2020
Publication in conjunction with Department of Chemical Engineering and Materials Science
Aluminum-Based Initiators from Thiols for Epoxide Polymerizations Niloofar Safaie, Bandana Rawal, Kohji Ohno*, and Robert C. Ferrier Jr.* Macromolecules, 2020, 19, 8181–8191.
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October 8, 2020
Publication in conjunction with Department of Chemical Engineering and Materials Science
Extraordinary Phase Coherence Length in Epitaxial Halide Perovskites. K. Nasyedkin, I. King, L. Shang, P. Chen, L.Wang, R.J. Staples, K. Sun, R.R. Lunt, J. Pollanen Condensed Matter , 2020, 1-23.
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September 14, 2020
Publication in conjunction with University of Idaho, Chemistry Department
Challenging the limits of nitrogen and oxygen content of fused rings Hu, L; Gao, HX and Shreeve, JM Journal of Materials Chemistry A, 2020, 8(34), 1711-17414.
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AUGUST 18, 2020
New Microscope Funded By Almuni!.
NEW Zeiss Discovery Microscope V20 was purchased with Funds from Dr. James Hoeschele, former MSU Researcher working on cis-Platinum system. Please join us in thanking Dr. James Hoeschele for his generosity!
Click Here To See more on Dr. James Hoeshele
August 18, 2020
New Microscope Funded By Almuni!
NEW Zeiss Discovery Microscope V20 was purchased with Funds from Dr. James Hoeschele, former MSU Researcher working on cis-Platinum system. Please join us in thanking Dr. James Hoeschele for his generosity!
Click Here for More About Dr. James Hoeshele
May 16, 2020
Submission of Online Form Required for Data Collection or Samples Submission
We are currently requiring a submission of the online form and an appointment to use facilities. Generate a Chemdraw image file of your compound before going to submission page. PXRD Users Email before making a schedule use of the instrument.
Click Here for Submission Page
February 20, 2020
New Synergy Diffractometer is operational in the CCR, MSU Department of Chemistry
The Rigaku Synergy S Diffractometer was purchased with Support from the MRI program by the National Science Foundation under Grant No. 1919565.
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August 20, 2020
Publication in conjunction with Grand Valley State University
Syntheses and crystal structures of anhydride 4-oxatetracyclo{5.3.2.02,6.08,10]dodec-11-ene- 3,5-dione and the related imide 4-(4-bromophenyl)-4-azatetracyclo[5.3.2.02,6.08,10]dodec-11-ene-3,5-dione" A. Hulsman, I. Lorenzana, T. Schultz, B. Squires, B.A. Stenfors, M. Tolonen, R.J. Staples, S.M. Biros, W.R. Winchester Acta Cryst., 2020, E76, 1311-1315.
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June 28, 2020
Publication in conjunction with Grand Valley State University
Two beta-phosphorylamide compounds as ligands for Sm3+, Eu3+ and Tb3+: X-Ray crystallography and luminescence properties A.R. Lear, J. Lenters, M.G. Patterson, R.J. Staples, E.J. Werner, S.M. Biros Molecules, 2020, 25, 2971.
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June 15, 2020
Publication in conjunction with Grand Valley State University
Synthesis and Crystallographic Characterization of X-Substituted 2,4-Dinitrophenyl-40-phenylbenzenesulfonates B.A. Stenfors, R.J. Staples, S.M. Biros, F.N. Ngassa Chemistry, 2020, 2, 591-599.
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June 24, 2020
Publication in conjunction with Michigan State University:
Asymmetric Catalytic Meerwein-Ponndorf-Verley Reduction of Ketones¬ with Aluminum(III)-VANOL Catalysts" L. Zheng, X. Yin, A. Mohammadlou, R. Sullivan, Y. Guan, R.J. Staples, W.D. Wulff ACS Catalysis, 2020, 52, 7188-7194.
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May 4, 2020
Publication in conjunction with Calvin College
The Synthesis of Functionalized 3-Aryl- and 3-Heteroaryloxazolidin-2-ones and Tetrahydro-3-Aryl-1,3-oxazin-2-ones via the Iodocyclocarbamation Reaction. Access to Privileged Chemical Structures and Scope and Limitations of the Method. A. Bell, A. Boomsma, N. Flikweert, R. Hohlman, S Zhang, R. Blankespoor, S.M. Biros, R.J. Staples, S. Brickner, M. Barbachyn Journal of Organic Chemistry, 2020, 85(10), 6323-6337.
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March 24, 2020
Publication in conjunction with Michigan State University:
"Catalytic Asymmetric Aziridination of Benzhydryl Imines and Diazo Acetate Esters with BOROX Catalysts from 3,3’- Disubstituted VANOL Ligands." Y. Guan, Z. Lu, X. Yin, A. Mohammadlou, R.J. Staples, W.D. Wulff Synthesis, 2020, 52, 2073-2091.
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March 20, 2020
Publication in conjunction with Michigan State University:
"Low-Spin Cobalt(II) Redox Shuttle by Isocyanide Coordination." A.L. Raithel, T.-Y. Kim, K. Nielsen, R.J. Staples, T.W. Hamann Sustainable Energy & Fuels, 2020,4(5), 2497-2507.
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February 20, 2020
Publication in conjunction with Grand Valley State University:
"Crystal structure of 4-methyl-N-(4-methylbenzyl)benzenesulfonamide." B.A. Stenfors, R.J. Staples, S.M. Biros, F.N. Ngassa Acta Cryst., 2020, E76, 235-238
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January 29, 2020
ACA Refelctions News Letter
American Crystallographic associtation offers its News Letter RefleXions to all of the public via their web page. The Winter copy now available. Contains information for San Diego Summer Meeting (Aug 2- Aug 7, 2020).
Read it Here
January 24, 2020
Publication in conjunction with MSU, Department of Plant Biology
"Structure and chemical analysis of major specialized metabolites produced by the lichen Evernia prunastri." R. Staples, R.L. Laduca, L. Roze, R. Beaudry, A. Fryday, AV. Koptina, A.L. Schilmiller, B. Smith, J.E. Linz, M. Laivenieks, F. Trail, Chem. Biodivers., 2020, 17(1), e1900465.
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January 24, 2020
Publication in conjunction with Wayne State University
"Synthesis of Chromium(II) Complexes with Chelating Bis(alkoxide) Ligand and Their Reactions with Organoazides and Diazoalkanes." S.S. Kurup, R.J.Staples, R.L.Lord, S. Groysman Molecules 2020, 25, 273-280.
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