MICHIGAN STATE UNIVERSITY Department of Chemistry

NEWS

May , 2023
Publication in conjunction with MSU CHEMISTRY
Thiol and H2S-Mediated NO Generation from Nitrate at Copper(II) P. Ghosh, M. Stauffer, M.E. Ahmed, J.A. Bertke, R.J. Staples, T.H. Warren JACS , 2023, xxx, ASAP.
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January , 2023
Publication Of First protien Collected on New Synergy Diffractometer
A Crosslinked Ionic Organic Framework for Efficient Iodine and Iodide Remediation in Water. Maity, S., Bingham, C., Sheng, W., Ehyaei, N., Chakraborty, D., Tahmasebi-Nick, S., Kimmel, T.E., Vasileiou, C., Geiger, J.H., Borhan, B. Analysis , 2023, 148, 1085.
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March 21, 2023
Publication in conjunction with MSU CHEMISTRY
A rare isocyanide derived from an unprecedented neutral yttrium(ii) bis(amide) complex R. Jena, F. Benner, F. Delano (IV), D. Holmes, J. McCracken, S. Demir, A. Odom Chem. Science , 2023,14, 4257-4264.
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March 22, 2023
Publication in conjunction with Grand Valley State University
A mixed phosphine sulfide/selenide structure as an instructional example for how to evaluate the quality of a model S. Parkin. J. Cunningham, B. Rawls, J.E. Bender, R.J. Staples, S.M. Biros ACTA E , 2023, E79, 28-32.
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March 8, 2023
Publication in conjunction with Grand Valley State University
Crystal structure of tert-butyl 3,6-diiodocarbazole-9-carboxylate E.N. Sielaff, R.J. Staples, S.M. Biros ACTA E , 2023, E79, 345-348.
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February 27, 2023, 2023
Publication in conjunction with University of Idaho
Bisnitramide-Bridged N-Substituted Tetrazoles with Balanced Sensitivity and High Performance A.K. Chinnam, R.J. Staples, J.M. Shreeve Org. Lett., 2023, 25, 1481-1485 .
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February 22, 2023, 2023
Publication in conjunction with University of Idaho
Design and synthesis of phenylene-bridged isoxazole and tetrazole-1-ol based energetic materials of low sensitivity S. Lal, R.J. Staples, J.M. Shreeve Dalton Trans. , 2023, 52(11), 3449-3457.
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February 8, 2023
Publication in conjunction with University of Idaho
Increasing the limits of energy and safety in tetrazoles: dioximes as unusual precursors to very thermostable and insensitive energetic materials J. Singh, R.J. Staples, J.M. Shreeve J. Mater. Chem. A , 2023, ASAP .
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January 30, 2023
Publication in conjunction with MSU Department of Chemistry
Guanidinate Rare-Earth Tetraphenylborate Complexes and Their Prospects in Single-Molecule Magnetism F. Delano IV, S. Demir Cryst. Growth Des. , 2023, ASAP.
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January 23, 2023
Publication in conjunction with MSU Department of Chemistry
Linear, Electron-Rich, Homoleptic Rare Earth Metallocene and Its Redox Activity E. Castellanos, S. Demir Inorg. Chem. , 2023, ASAP.
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January 19, 2023
Publication in conjunction with MSU Department of Chemistry
Molecular Switch Cobalt Redox Shuttle with a Tunable Hexadentate Ligand A.L. Raithel, W.E. Meador, T-Y Kim, R.J. Staples, J.H. Delcamp, T.W. Hamann J. Amer. Chem. Soc. , 2023, 145(2), 1367-1377.
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December 15, 2022
Publication in conjunction with Western New Englang University
Photoswitching Properties of 5-Methoxy-2-(2-phenyldiazenyl) Pyridine. J.T. Foy, N. Ta, J. Hoyt, R.J. Staples, C. Ehm, Chemistry Select , 2022, 7(47), e202204517.
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December 20, 2022
Publication in conjunction with University of Idaho, Chemistry Department
Balancing Energy and Stability of Nitroamino-1,2,4-Oxadiazoles through a Planar Bridge. J. Singh, Staples, Richard, J. J.M. Shreeve Organic Letters, 2022, 24(48), 8832-8836..
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December 1, 2022



New HIGH Pressure Synergy Diffractometer is operational in the CCR, Professor Weiwei Xie purchased athis system to perfrom Hign Pressure Crystallography here at MSU.
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November 24, 2022
Publication in conjunction with Dartmouth College
A Crosslinked Ionic Organic Framework for Efficient Iodine and Iodide Remediation in Water. M. Zhang, J Samanta, B.A. Atterberry, R.J. Staples, Richard, A.J. Rossini, C. Ke Angew Chem. Int. Ed. , 2022,61, e20221489.
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November 7 23, 2022
Publication in conjunction with University of Idaho, Chemistry Department
Effects of nitric acid concentration for nitration of fused [1,2,5]oxadiazolo[3,4-d]pyrimidine-5,7-diamine A.K. Chinnam, Y. Tang, R.J. Staples, Richard, J. J.M. Shreeve Dalton Trans., 2022, 51(47), 17987-17993.
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October 23, 2022
Publication in conjunction with University of Idaho, Chemistry Department
Highly Selective Nitroamino Isomerization Guided by Proton Transport Dynamics: Full-Nitroamino Imidazole[4,5-d]pyridazine Fused-Ring System Y. Wang, L. Hu, R.J. Staples, Richard, S. Pang, J. J.M. Shreeve Appl. Mater. Interfaces, 2022, 14(47), 52971-52978.
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October 7, 2022
Publication in conjunction with University of Idaho, Chemistry Department
FOX-7 based nitrogen rich green energetic salts: Synthesis, characterization, propulsive and detonation performance S. Lal, R.J. Staples, J.M. Shreeve Chem. Eng. J., 2023, 139600.
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October 4, 2022
Publication in conjunction with University of Idaho, Chemistry Department
Energetic Salts of Sensitive N,N′-(3,5-Dinitropyrazine-2,6-diyl)dinitramide Stabilized through Three-Dimensional Intermolecular Interactions J. Singh, A.K. Chinnam, R.J. Staples, J.M. Shreeve Inorganic Chemistry, 2022, 61(41), 1643-16500.
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October, 2022
Publication in conjunction with Grand Valley State University, Chemistry Department
Crystal structure of chlorido[diphenyl(thiophen-2-yl)phosphine-κP]gold(I) T. Neils, A. LaDuca, J.E. Bender, R.J. Staples, S.M. Biros Acta Cryst E., 2022, 78(10), 1044-11047.
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October, 17, 2022
Publication in conjunction with Dartmouth University, Chemistry Department
Construction of Highly Thermostable and Insensitive Three-Dimensional Energetic Salts Based on [1,2,5]Oxadiazolo[3,4-d]pyrimidine J. Samanta, R.W. Dorn, W. Zhang, X. Jiang, M. Zhang, R.J. Staples, A.J. Rosini, C. Ke. Organic letters, 2022, 8(10), 2678-2687.
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July 18, 2022
Publication in conjunction with Calvin College
Synthesis of Ester-Substituted Indolizines from 2-Propargyloxypyridines and 1,3-Dicarbonyls H. Bos, D. Dreher, C. Hartgernink, C. Colin, R.J. Staples, C. Anderson The Journal Of Organic Chemistry , 2022, 87(15), 10241-10249.
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July 11, 2022
Publication in conjunction with Univeristy of Idaho
Synthesis of a high-energy-density material through rapid replacement of crystal water of hydrates. J. Zhang, Y. Feng, Y. Bo, A.K. Chinnam, J. Singh , R.J. Staples, X. He, K. Wang, J. Zhang, J.M. Shreeve Chem , 2022, 8(1), 2678-2687.
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June 24, 2022
Publication in conjunction with MSU Department of Chemistry
Ligand-Field Spectroscopy of Co(III) Complexes and the Development of a Spectrochemical Series for Low-Spin d6 Charge-Transfer Chromophores J.T. Yarranton, J.K. McCusker J. Am. Chem. Soc. , 2022, 144(27), 12488-12500.
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June 23, 2022
Publication in conjunction with University of Idaho
Engineering bistetrazoles:(E)-5,5’-(ethene-1,2-diyl)bis(1H-tetrazol-1-ol) as a new planar high-energy-density material J. Singh , R.J. Staples, J.M. Shreeve Material advances , 2022, 3(14), 6062-6068.
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June, 6, 2022
Publication in conjunction with Grand Valley State University
Synthesis of diphenyl-(2-Thienyl)phosphine, its chalcogenide derivatives and a series of novel complexes of lanthanide nitrates and triflates. T. Luster, H.J. Van de Roovaart, K.J. Korman, G. G. Sands, K.M. Dunn, A. Spyker, R.J. Staples, S. M. Biros, J.E. Bender Dalton Tran. Front., 2022, 51, 9103-9115.
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May 18, 2022
Publication in conjunction with Dartmouth College
Asymmetric De Novo Synthesis of a Cucurbitane Triterpenoid: Total Synthesis of Octanorcucurbitacin B Bucknam, AR and Micalizio, GC J. Am. Chem. Soc. , 2022, 144(19), 5818-5829..
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May 10, 2022
Publication in conjunction with University of Idaho, Chemistry Department
Nitro-based and nitro-free tri-cationic azole salts: a unique class of energetic green tri-ionic salts obtained from the reaction with nitrogen-rich bases A.K. Chinnam, R.J. Staples, G. Zhao, J.M. Shreeve Materials Advances, 2022, 3(12), 5012-5018.
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April 16, 2022
Publication in conjunction with MSU Department of Chemistry
Investigation of phosphine donor properties to vanadium(V) nitrides L. Mo, H.I.Barr, A.L. Odom Results in Chemistry , 2022, 4, 100344.
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April , 2022
Publication in conjunction with MSU Department of Chemistry
Isolation of the elusive bisbenzimidazole Bbim(3-center dot) radical anion and its employment in a metal complex Benner, F and Demir, S Chemical Science , 2022, 13(20), 5818-5829..
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April 13, 2022
Publication in conjunction with University of Idaho, Chemistry Department
pH-Controlled forms of 1-amino-1-hydrazino-2,2-dinitroethylene (HFOX): selective reactivity of amine and hydrazinyl groups with aldehydes or ketones A.K. Chinnam, R.J. Staples, J.M. Shreeve Materials Advances , 2022, 3(10), 4289-4294.
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April 1, 2022
Publication in conjunction with University of Idaho, Chemistry Department
Bis(3-(trinitromethyl)-1H-1,2,4-triazol-5-yl)methanone: A mildly acidic high-performing energetic material A.K. Chinnam, J. Singh, R.J. Staples, J.M. Shreeve Chem. Eng. Journal, 2022, 433, 13352.
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March 1, 2022
Publication in conjunction with University of Idaho, Chemistry Department
Pyrazole bridges ensure highly stable and insensitive bistetrazoles J. Singeh, J.P. Hooper, J.M Shreeve Chem. Eng. Journal, 2022, 431 (part4), 133282.
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Feb 22, 2022
Publication in conjunction with University of Idaho, Chemistry Department
Functionalized planar aromatic rings as precursors to energetic N,N′-(4,6-dinitro-1,3-phenylene)dinitramide and its salts J. Singh, S. Sohan, R.J. Staples, J.M. Shreeve Materials Chemistry Frontiers, 2022, 6(7), 933-938.
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February 9, 2022
Publication in conjunction with MSU Department of Chemistry
Steric Shielding Effects Induced by Intramolecular C–H···O Hydrogen Bonding: Remote Borylation Directed by Bpin Groups J.R.M.Bastidas, A. Chhabra, Y. Feng,T.J. Oleskey, M.R. Smith III, and R.E. Maleczka Jr. ACS Catal. , 2022, 12(4), 2694-2705.
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January 18, 2022
Publication in conjunction with MSU Department of Chemistry
Heteroleptic Rare-Earth Tris(metallocenes) Containing a Dibenzocyclooctatetraene Dianion. E.R. Pugliese, F. Benner, E. Castellano, F. Delano IV, S. Demir Inorg. Chem., 2022, 61, 2444-2454.
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January 13, 2022
Publication in conjunction with Dartmouth University, Chemistry Department
An ultra-dynamic anion-cluster-based organic framework J. Samanta, R.W. Dorn, W. Zhang, X. Jiang, M. Zhang, R.J. Staples, A.J. Rosini, C. Ke. ACS Chem., 2022, 8(1), 253-267.
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January 21, 2022
Publication in conjunction with Department of Chemistry
Taming Salophen in Rare Earth Metallocene Chemistry. E. Castellano, F. Benner, S. Demir Inorg. Chem. Front., 2022, 9(7), 1325-1336.
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