McCusker Group Publications
| 2024 | ||
| "Establishing the origin of Marcus-inverted-region behaviour in the excited-state dynamics of cobalt(III) polypyridyl complexes" Ghosh, A.; Yarranton, J. T.; McCusker, J. K. Nat. Chem. 2024, 16, 1665-1672. | ||
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| 2023 | ||
| "Observation of parallel intersystem crossing and charge transfer-state dynamics in [Fe(bpy)3]2+ from ultrafast 2D electronic spectroscopy" Lee, A.; Son, M.; Deegbey, M.; Woodhouse, M. D.; Hart, S. M.; Beissel, H. F.; Cesana, P. T.; Jakubikova, E.; McCusker, J. K.; Schlau-Cohen, G. S. Chem. Sci. 2023, 14, 13140-13150. | ||
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| "Exploiting the Marcus inverted region for first-row transition metal-based photoredox catalysis" Chan, A. Y.; Ghosh, A.; Yarranton, J. T.; Twilton, J.; Jin, J.; Arias-Rotondo, D. M.; Sakai, H. A.; McCusker, J. K.; MacMillan, D. W. C. Science 2023, 384, 191-197. | ||
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| "Direct Evidence for Excited Ligand Field State-based Oxidative Photoredox Chemistry of Cobalt(III) Polypyridyl Photosensitizer" Alowakennu, M. M.; Ghosh, A.; McCusker, J. K. J. Am. Chem. Soc. 2023, 145, 20786-20791. | ||
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| 2022 | ||
| "Ligand-Field Spectroscopy of Co(III) Complexes and the Development of a Spectrochemical Series for Low-Spin d6 Charge-Transfer Chromophores" Yarranton, J. T.; McCusker, J. K. J. Am. Chem. Soc. 2022, 144, 12488-12500. | ||
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| "On the use of vibronic coherence to
identify reaction coordinates for ultrafast
excited-state dyanmics of transition metal-based
chromophores" Paulus, B. C.; McCusker, J. K. Faraday
Discuss. 2022, 237, 274-299. |
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| "Ion-Pair Reorganization Regulates Reactivity in Photoredox Catalysts" Earley, J. D.; Zieleniewska, A.; Ripberger, H. H.; Shin, N. Y.; Lazorski, M. S.; Mast, Z. J.; Sayre, H. J.; McCusker, J. K.; Scholes, G. D.; Knowles, R. R.; Reid, O. G.; Rumbles, G. Nat. Chem. 2022, 14, 746-753. | ||
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| 2021 |
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| "A Modular Approach to Light Capture and Synthetic Tuning of the Excited-State Properties of Fe(II)-Based Chromophores" Paulus, B. C.; Nielsen, K. C.; Tichnell, C. R.; Carey, M. C.; McCusker, J, K. J. Am. Chem. Soc. 2021, 143, 8086-8098. | ||
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| "Optical and Infrared
Spectroelectrochemical Studies of CN-Substituted
Bipyridyl Complexes of Ruthenium(II)" Taylor, J. O.;
Pižl, M.; Kloz, M.; Rebarz, M.; McCusker, C. E.;
McCusker, J. K. Záliš, S.; Hartl, F.; Vlček, A. Inorg.
Chem. 2021, 60, 3514-3523. |
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| 2020 | ||
| "Mechanistic Origin of Photoredox
Catalysis Involving Iron(II) Polypyridyl
Chromophores" Woodhouse, M. D.; McCusker, J. K. J.
Am. Chem. Soc. 2020, 142,
16229-16233. |
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| "Exploiting Chemistry and Molecular Systems for Quantum Information Science" Wasielewski, M. R.; Forbes, M. D. E.; Frank, N. L.; Kowalski, K.; Scholes, G. D.; Yuen-Zhou, J.; Baldo, M. A.; Freedman, D. E. Goldsmith, R. H.; Goodson III, T.; Kirk, M. L.; McCusker, J. K.; Ogilvie, J. P.; Shultz, D. A.; Stoll, S.; Whaley, B. Nat. Rev. Chem. 2020, https://doi.org/10.1038/s41570-020-0200-5. | ||
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| "Leveraging Excited-State Coherence
for Synthetic Control of Ultrafast Dynamics" Paulus,
B. C.; Adelman, S. L; Jamula, L. L.; McCusker, J. K.
Nature 2020, 582, 214-219. |
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| "Outer-Sphere Effects
on Ligand-Field Excited-State Dynamics: Solvent
Dependence of High-Spin to Low-Spin Conversion in
[Fe(bpy)3]2+" Miller, J. N.;
McCusker, J. K. Chem.
Sci. 2020,
11, 5191-5204. |
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| "Influence of
Electrolyte Composition on Ultrafast Interfacial
Electron Transfer in Fe-Sensitized TiO2-Based
Solar Cells" Tichnell, C. R.; Miller, J. N.; Liu,
C.; Mukherjee, S.; Jakubikova, E.;
McCusker, J. K. J.
Phys. Chem. C 2020, 124, 1794-1811. |
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| 2019 | ||
| "Using Ultrafast
X-ray Spectroscopy To Address Questions in
Ligand-Field Theory: The Excited State Spin and
Structure of [Fe(dcpp)2]2+"
Britz, A.; Gawelda, W.; Assefa, T. A.; Jamula, L.
L.; Yarranton, J. T.; Galler, A.; Khakhulin, D.;
Diez, M.; Harder, M.; Doumy, G.; March, A. M.;
Bajnóczi, E.; Németh, Z.; Pápai, M.; Rozsályi, E.;
Szemes, D. S.; Cho, H.; Mukherjee, S.; Liu, C.; Kim,
T. K.; Schoenlein, R. W.; Southworth, S. H.; Young,
L.; Jakubikova, E.; Huse, N.; Vankó, G.; Bressler,
C.; McCusker, J. K. Inorg. Chem. 2019, 58, 9341-9350. |
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| "Electronic structure in the transition metal block and its implications for light harvesting" McCusker, J. K. Science 2019, 363, 484-488. | ||
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| "Insights into the excited state dynamics of Fe(II) polypyridyl complexes from variable-temperature ultrafast spectroscopy" Carey, M. C.; Adelman, S. L.; McCusker, J. K. Chem. Sci. 2019, 10, 134. | ||
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| 2018 | ||
| "Vibrational Relaxation and Redistribution
Dynamics in Ruthenium(II) Polypyridyl-Based
Charge-Transfer Excited States: A Combined
Electronic and Infrared Absorption Study" Brown, A.
M.; McCusker, C. E.; Carey, M. C.; Blanco-Rodríguez,
A. M.; Towrie, M.; Clark, I. P.; Vlček, A.;
McCusker, J. K. J.
Phys. Chem. A 2018, 122, 7941-7953. |
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| 2017 | ||
| "Using coherence to enhance function in chemical and biophysical systems" Scholes, G. D.; Fleming, G. R.; Chen, L. X.; Aspuru-Guzik, A.; Buchleitner, A.; Coker, D. F.; Engel, G. S.; van Grandelle, R.; Ishizaki, A.; Jonas, D. M.; Lundeen, J. S.; McCusker, J. K.; Mukamel, S.; Ogilvie, J. P.; Olaya-Castro, A.; Ratner, M. A.; Spano, F. C.; Whaley, K. B.; Zhu, X. Nature 2017, 543, 647-656. | ||
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| "Photosensitized, energy transfer-mediated organometallic catalysis through electronically excited nickel(II)" Welin, E. R.; Le, C.; Arias-Rotondo, D. M.; McCusker, J. K.; MacMillan, D. W. C. Science 2017, 355, 380-385. | ||
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| 2016 | ||
| "The photophysics of photoredox catalysis: a roadmap for catalyst design" Arias-Rotondo, D. M.; McCusker, J. K. Chem. Soc. Rev. 2016, 45, 5803-5820. | ||
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| 2015 | ||
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“Ultrafast excited-state processes in
inorganic systems” McCusker, J. K.; Vlček, Jr., A. Acc.
Chem. Res. 2015, 48,
1207-1208.
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article |
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| 2014 | ||
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“Spectroelectrochemical identification
of charge-transfer excited states in
transition metal-based polypyridyl complexes”
Brown, A. M.; McCusker, C. E.; McCusker, J. K.
Dalton Trans. 2014,
43,
17635-17646.
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article |
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“X-ray spectroscopy: Enlightened
state” McCusker, J. K. Nat. Phys. 2014, 10,
476-477.
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article |
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“Synthesis and characterization of a
high-symmetry ferrous polypyridyl complex:
Approaching the 5T2/3T1
crossing point for FeII” Jamula, L.
L.; Brown, A. M.; Guo, D.; McCusker, J. K. Inorg. Chem. 2014, 53,
15-17.
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article |
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| 2012 | ||
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“Ligand-field symmetry effects in
Fe(II) polypyridyl compounds probed by
transient X-ray absorption spectroscopy” Cho,
H.; Strader, M. L.; Hong, K.; Jamula, L.;
Gullikson, E. M.; Kim, T. K.; de Groot, F. M.
F.; McCusker, J. K.; Schoenlein, R. W.; Hus,
N. Faraday Discuss. 2012,
157,
463-474.
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article |
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| 2011 | ||
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“Angular momentum conservation in
dipolar energy transfer” Guo, D.; Knight, T.
E.; McCusker, J. K. Science 2011,
334,
1684-1687.
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article |
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“Femtosecond soft X-ray spectroscopy
of solvated transition-metal complexes:
Deciphering the interplay of electronic and
structural dynamics” Huse, N.; Cho, H.; Hong,
K.; Jamula, L.; de Groot, F. M. F.; Kim, T.
K.; McCusker, J. K.; Schoenlein, R. W. J. Phys. Chem.
Lett. 2011, 2,
880-884.
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article |
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“Synthesis and spectroscopic
characterization of CN-substituted bipyridyl
complexes of Ru(II)” McCusker, C. E.;
McCusker, J. K. Inorg. Chem. 2011,
50,
1656-1669.
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article |
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| 2010 | ||
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“Vibrational coherence in the excited
state dynamics of Cr(acac)3:
Probing the reaction coordinate for ultrafast
intersystem crossing” Schrauben, J. N.;
Dillman, K. L.; Beck, W. F.; McCusker, J. K. Chem. Sci. 2010,
1,
405-410.
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article |
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“Photo-induced spin-state conversion
in solvated transition metal complexes probed
via time-resolved soft X-ray spectroscopy” Huse, N.; Kim, T. K.; Jamula, L.;
McCusker, J. K.; de Groot, F. M. F.; Schoenlein, R. W. J.
Am. Chem. Soc. 2010, 132, 6809-6816.
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article |
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“Orbital-specific energy transfer” Knight T. E.; McCusker, J. K. J.
Am. Chem. Soc. 2010, 132,
2208-2221.
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article |
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| 2009 | ||
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“Differential polarization of spin and
charge density in substituted phenoxy
radicals” Fehir, Jr., R. J.; McCusker, J. K. J.
Phys. Chem. A 2009, 113,
9249-9260.
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article |
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| 2008 | ||
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“Femtosecond
time-resolved optical and Raman spectroscopy
of photoinduced spin crossover: Temporal
resolution of low-to-high spin optical
switching” Smeigh, A. L.; Creelman, M.;
Mathies, R. A.; McCusker, J. K. J. Am. Chem. Soc.
2008, 130,
14105-14107.
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article |
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“Electronic structure of [Ga2(tren)2(CAsq,cat)](BPh4)2(BF4):
An
EPR, ENDOR, and density functional study”
Schrauben, J. N.; Guo, D.; McCracken, J. L.;
McCusker, J. K. Inorg. Chim. Acta
2008, 361,
3539-3547.
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article |
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“Energy transfer dynamics in ReI−based
polynuclear assemblies: A quantitative
application of F�rster theory” Knight, T. E.; Guo, D.; Claude, J. P.;
McCusker, J. K. Inorg. Chem. 2008,
47, 7249-7261.
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article |
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“Effect of the presence of iodide on
the electron injection dynamics of
dye-sensitized TiO2-based solar
cells” Smeigh, A. L.; Katz, J. E.;
Brunschwig, B. S.; Lewis, N. S.; McCusker, J.
K. J. Phys. Chem. C 2008,
112, 12065-12068.
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article |
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“Distinguishing between Dexter and
rapid sequential electron transfer in
covalently linked donor−acceptor assemblies” Soler, M.; McCusker, J. K. J.
Am. Chem. Soc. 2008, 130, 4708-4724.
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article |
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| 2007 | ||
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“Spin exchange effects on the
physicochemical properties of
tetraoxolene-bridged bimetallic complexes” Guo, D.; McCusker, J. K. Inorg.
Chem. 2007, 46,
3257-3274.
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article |
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| 2006 | ||
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“Picosecond X-ray absorption
spectroscopy of a photoinduced iron(II) spin
crossover reaction in solution” Khalil, M.; Marcus, M. A.; Smeigh, A.
L.; McCusker, J. K.; Chong, H. H. W.;
Schoenlein, R. W. J.
Phys. Chem. A 2006, 110,
38-44.
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article |
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“Ultrafast dynamics of ligand-field
excited states” Juban, E. A.; Smeigh, A. L.;
Monat, J. E.; McCusker, J. K. Coord.
Chem. Rev. 2006, 250, 1783-1791.
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article |
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| 2005 | ||
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“Intramolecular energy transfer
involving Heisenberg spin-coupled dinuclear
iron−oxo complexes” Picraux, L. B.;
Smeigh, A. L.; Guo, D.; McCusker, J. K. Inorg.
Chem. 2005, 44,
7846-7859.
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article |
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“Ultrafast dynamics of 2E
state formation in Cr(acac)3” Juban E. A.; McCusker, J. K. J.
Am. Chem. Soc. 2005, 127,
6857-6865.
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article |
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| 2004 | ||
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“Time-resolved relaxation studies of
spin crossover systems in solution” Brady, C.; McGarvey,
J. J.; McCusker, J. K.; Hendrickson, D. N. Top.
Curr. Chem. 2004, 235, 1-22.
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article |
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| 2003 | ||
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“Intramolecular excimer formation in a
naphthalene-appended dinuclear iron−oxo
complex” Picraux, L. B.; Weldon, B. T.;
McCusker, J. K. Inorg. Chem. 2003,
42, 273-282.
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article |
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“Femtosecond absorption spectroscopy
of transition metal charge-transfer complexes”
McCusker, J. K. Acc.
Chem.
Res. 2003, 36,
876-887.
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article |
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| 2002 | ||
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“Transient absorption spectroscopy of
ruthenium and osmium polypyridyl complexes
adsorbed onto nanocrystalline TiO2
photoelectrodes” Kuciauskas, D.; Monat, J. E.;
Villahermosa, R.; Gray, H. B.; Lewis, N. S.;
McCusker, J. K. J. Phys. Chem. B 2002,
106, 9347-9358.
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article |
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“Ground- and excited-state electronic
structures of the solar cell sensitizer
bis(4,4'-dicarboxylato-2,2'-bipyridine)bis(isothiocyanato)ruthenium(II)”
Monat, J. E.; Rodriguez, J. H.;
McCusker, J. K. J. Phys. Chem. A 2002,
106, 7399-7406.
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article |
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“Synthesis of mono-substituted
2,2'-bipyridines” Cordaro, J. G.; McCusker, J. K.;
Bergman, R. G. Chem. Commun. 2002,
1496-1497.
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article |
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“Density functional theory of
spin-coupled models for diiron-oxo proteins:
Effects of oxo and hydroxo bridging on
geometry, electronic structure, and magnetism”
Rodriguez, J. H.; McCusker, J. K. J. Chem. Phys. 2002, 116, 6253-6270.
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article |
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| 2001 | ||
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“Bimolecular electron and energy
transfer reactivity of exchange-coupled
dinuclear iron(III) complexes” Weldon, B. T.;
Wheeler, D. E.; Kirby, J. P.; McCusker, J.
K. Inorg.
Chem. 2001, 40,
6802-6812.
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article |
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“Fuel from photons” McCusker, J. K. Science 2001,
293,
1599-1601.
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article |
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“Attenuated total reflection design
for in situ FT-IR spectroelectrochemical
studies” Visser, H.; Curtright, A. E.;
McCusker, J. K.; Sauer, K. Anal. Chem. 2001,
73, 4374-4378.
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article |
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| 2000 | ||
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“Blue-fluorescent antibodies”
Simeonov, A.; Matsushita, M. Juban, E. A.;
Thompson, E. H.
Z.; Hoffman, T. Z.; Beuscher, IV, Albert E.;
Taylor, M. J.; Wirsching, P.; Rettig, W.;
McCusker, J. K.;
Stevens, R. C.; Millar, D. P.; Schultz, P. G.;
Lerner, R. A.; Janda, K. D. Science
2000,
290,
307-313.
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article |
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“Ultrafast electron localization
dynamics following photo-induced charge
transfer” Yeh, A. T.; Shank, C. V.; McCusker,
J. K. Science 2000, 289,
935-938.
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article |
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“Femtosecond
excited-state dynamics of an iron(II)
polypyridyl solar cell sensitizer model”
Monat, J. E.; McCusker, J. K. J.
Am. Chem. Soc. 2000, 122,
4092-4097.
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article |
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| 1999 | ||
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“Density functional theory analysis of
electronic structure variations across the
orthoquinone/semiquinone/catechol redox
series” Wheeler, D. E.; Rodriguez, J. H.;
McCusker, J. K. J. Phys. Chem. A 1999, 103,
4101-4112.
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article |
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“Variable-temperature emission studies
of solvation dynamics: Evidence for coupling of solvation to
chromophore structural dynamics in the
evolution of charge-transfer excited states” Damrauer, N. H.; McCusker, J. K. Inorg.
Chem. 1999, 38,
4268-4277.
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article |
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“Ultrafast dynamics in the
metal-to-ligand charge transfer excited-state
evolution of
[Ru(4,4'-diphenyl-2,2'-bipyridine)3]2+”
Damrauer, N. H.; McCusker, J. K. J.
Phys. Chem. A 1999, 103,
8440-8446.
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article |
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“Static and
time-resolved spectroscopic studies of
low-symmetry Ru(II) polypyridyl complexes” Curtright, A. E.; McCusker, J. K. J.
Phys. Chem. A 1999, 103,
7032-7041.
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article |
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| 1998 | ||
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“Theoretical
studies of steric effects on intraligand
electron delocalization: Implications for the
temporal evolution of MLCT excited states” Damrauer, N. H.; Weldon, B. T.;
McCusker, J. K. J. Phys. Chem. A 1998,
102, 3382-3397.
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article |
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“Electron
exchange and the photophysics of metal-quinone
complexes. 1. Synthesis and spectroscopy of
chromium-quinone dyads” Wheeler, D. E.; McCusker, J. K. Inorg.
Chem. 1998, 37,
2296-2307.
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article |
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“Experimental
observation of excited-state electron transfer
quenching involving exchange-coupled dinuclear
FeIII complexes” Kirby, J. P.; Weldon, B. T.; McCusker,
J. K. Inorg. Chem. 1998, 37,
3658-3659.
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article |
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“Density
functional studies of a Heisenberg spin
coupled chromium-semiquinone complex and its
chromium-catechol analog” Rodriguez, J. H.; Wheeler, D. E.;
McCusker, J. K. J. Am. Chem. Soc. 1998,
120,
12051-12068.
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article |
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| 1997 | ||
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“Effects of
intraligand electron delocalization, steric
tuning, and excited-state vibronic coupling on
the photophysics of aryl-substitued bipyridyl
complexes of Ru(II)” Damrauer, N. H.; Boussie, T. R.;
Devenney, M.; McCusker, J. K. J. Am. Chem.
Soc. 1997, 119,
8253-8268.
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article |
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“Femtosecond
dynamics of excited-state evolution in
[Ru(bpy)3]2+” Damrauer, N. H.; Cerullo, G.; Yeh, A.;
Boussie, T. R.; Shank, C. V.; McCusker, J. K.
Science
1997, 275, 54-57.
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