Reactions of Aldehydes & Ketones

Create a problem by selecting a reactant and a reagent from the lists on the right. When the Show Problem button is pressed a reaction will be shown on the left below. Using the drawing window above the reaction, draw a structural formula for the chief organic product formed in this reaction. If no reaction is expected, draw the starting structure.

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Reactants

propanal
acetophenone
cyclohexanone
benzaldehyde
3-pentanone
2-phenylethanal
2,2-dimethylpropiophenone
cyclopentanone
To review the chemistry of aldehydes & ketones Click Here.

Reagents

NaBH4
in alcohol

N2H4 (excess) + NaOR & heat
Wolff-Kishner reaction

HO-CH2CH2-OH
acid catalyst, heat (-H2O)

HCN  &
KCN catalyst

(CH2)5NH (piperidine )
acid catalyst, heat (-H2O)

C6H5NHNH2
acid catalyst, heat (-H2O)

(i) C6H5MgBr in ether
(ii) aqueous acid workup

( C6H5)3P=CH2
in ether soln.

(i) LiAlH4 in ether
(ii) aqueous acid workup

(i) C2H5Li in pentane soln
(ii) aqueous acid workup.

CrO3 in aqueous acid
Jones' reagent

NH2OH , acid catalyst
heat, (-H2O)