Publications 1.
“Synthesis and Structure-Activity
Relationships of Novel Arylfluoroquinolone
Antibacterial Agents” Chu, D. T. W.; Fernandes, P.
B.; Claiborne, A. K.; Pihuleac, E.; Nordeen, C.
W.; Maleczka, R. E., Jr.; Pernet, A. G. J. Med. Chem.
1985,
28,
1558–1564. (pdf) 2.
“Synthesis and Structure-Activity
Relationship of 1-Aryl-6,8-difluoroquinolone
Antibacterial Agents” Chu, D. T. W.; Fernandes, P.
B.; Maleczka, R. E., Jr.; Nordeen, C. W.; Pernet,
A. G. J. Med.
Chem. 1987,
30,
504–509. (pdf) 3.
“Synthesis of 4-Oxo-4H-quino[2,3,4-i,j][1,4]-benoxazine-5-carboxylic
Acid Derivatives” Chu, D. T. W.; Maleczka, R. E.,
Jr. J.
Heterocyclic Chem. 1987,
24,
453–456. (pdf) 4.
“Total Synthesis of Didemnins A, B, and C”
Rinehart, K. L.; Kishore, V.; Nagarajan, S.; Lake,
R. J.; Gloer, J. B.; Bozich, F. A.; Li, K.-M.;
Maleczka, R. E., Jr.; Todsen, T. L.; Munro, M. H.
G.; Sullins, D. W.; Sakai, R. J. Am. Chem. Soc.
1987,
109,
6846–6848. (pdf) 5.
“Synthesis of
4,12-Dihydro-4-oxoquino-[1,8a,8-a,b]quinoxaline-5-carboxylic
Acid
Derivatives” Chu, D. T. W.; Maleczka, R. E., Jr.;
Nordeen, C. W. J. Heterocyclic
Chem. 1988,
25,
927–930. (pdf)
6. “Enantioselective
Total
Synthesis of (–)-9-Epiambrox, a Potent
Ambergris-Type Olfactory Agent” Paquette, L. A.;
Maleczka, R. E., Jr. J. Org. Chem.
1991,
56,
912–913. (pdf) 7. “Regio- and
Stereoselective Oxidation of Unsaturated
Bicyclo[2.2.2]octanones with Selenium Dioxide”
Paquette, L. A.; Maleczka, R. E., Jr.; Qiu, F.-y.
J. Org. Chem.
1991,
56,
2455–2461. (pdf) 8. “Adaptation of
Oxyanionic Sigmatropy to the Convergent
Enantioselective Synthesis of Ambergris-Type
Odorants” Maleczka, R. E., Jr.; Paquette, L. A. J. Org. Chem.
1991,
56,
6538–6546. (pdf) 9.
“Enantioselective Construction of Natural
(+)-Pallescensin A. A Sigmatropic Pathway to
Furanosequeterpines” Paquette, L. A.; Maleczka, R.
E., Jr. J.
Org. Chem. 1992,
57,
7118–7122. (pdf) 10.
“Rapamycin Synthetic Studies. 1.
Construction of the C(27) to C(42) Subunit” Smith,
A. B., III; Condon, S. M.; McCauley, J. A.; Leahy,
J. W.; Leazer, J. L., Jr.; Maleczka, R. E., Jr. Tetrahedron Lett.
1994,
35,
4907–4910. (pdf) 11.
“Rapamycin Synthetic Studies. 2.
Construction of the C(10) to C(26) Perimeter”
Smith, A. B., III; Maleczka, R. E., Jr.; Leazer,
J. L., Jr.; Leahy, J. W.; McCauley, J. A.; Condon,
S. M. Tetrahedron
Lett. 1994,
35,
4911–4914. (pdf) 12.
“Total Synthesis of Rapamycin and
Demethoxyrapamycin” Smith, A. B., III; Condon, S.
M.; McCauley, J. A.; Leazer, J. L., Jr.; Leahy, J.
W.; Maleczka, R. E., Jr. J. Am. Chem. Soc.
1995,
117,
5407–5408. (pdf) 13.
“A Unified Total Synthesis of the
Immunomodulators (–)-Rapamycin and
(–)-27-Demethoxyrapamycin: Construction of
the C(21–42) Perimeters” Smith, A. B., III;
Condon, S. M.; McCauley, J. A.; Leazer, J. L.,
Jr.; Leahy, J. W.; Maleczka, R. E., Jr. J. Am. Chem. Soc.
1997,
119,
947–961. (pdf)
14.
“A Unified Total Synthesis of the
Immunomodulators (–)-Rapamycin and
(–)-27-Demethoxyrapamycin: Assembly of the
Common C(1–20) Perimeter and Final Elaboration”
Smith, A. B., III; Condon, S. M.; McCauley, J. A.;
Leazer, J. L., Jr.; Leahy, J. W.; Maleczka, R. E.,
Jr. J. Am.
Chem. Soc. 1997,
119,
962–973. (pdf) 15.
“Stereospecificity of the 1,2-Wittig
Rearrangement: How Chelation Effects
Influence Stereochemical Outcome” Maleczka, R. E.,
Jr.; Geng, F. J.
Am. Chem. Soc. 1998,
120,
8551–8552. (pdf) 16.
“Development of a One Pot Palladium
Catalyzed Hydrostannylation/Stille Coupling
Protocol with Catalytic Amounts of Tin” Maleczka,
R. E., Jr.; Terstiege, I. J. Org. Chem.
1998,
63,
9622–9623. (pdf) 17.
“A New Approach for the Generation and
Reaction of Organotin Hydrides: The
Development of Reactions Catalytic in Tin”
Terstiege, I.; Maleczka, R. E., Jr. J. Org. Chem.
1999,
64,
342–343. (pdf) 18.
“Application of a Three-Carbon Ring
Expansion Process to Bridged Bicyclic Systems” Mi,
B.; Maleczka, R. E., Jr. Tetrahedron Lett. 1999,
40,
2053–2056. (pdf) 19.
“Synthetic Studies Toward Amphidinolide A:
Synthesis of Fully Functionalized Subunits”
Terrell, L. R.; Ward, J. S., III; Maleczka, R. E.,
Jr. Tetrahedron
Lett. 1999, 40,
3097–3100. (pdf) 20.
“Synthesis of Aryl and Alkyl Acylsilanes
Using Trimethyl(tributylstannyl)silane” Geng, F.;
Maleczka, R. E., Jr. Tetrahedron Lett. 1999, 40,
3113–3114. (pdf) 21. "Application
of Fluoride Catalyzed Silane Reductions of Tin
Halides to the in situ
Preparation of Vinylstannanes” Maleczka, R. E.,
Jr.; Terrell, L. R.; Clark, D. H.; Whitehead, S.
L.; Gallagher, W. P.; Terstiege, I. J. Org. Chem.
1999,
64,
5958–5965. (pdf) 22. “Synthesis and Fluoride
Promoted Wittig Rearrangements of
alpha-Alkoxysilanes” Maleczka, R. E., Jr.; Geng,
F. Org. Lett.
1999,
1,
1111–1113. (pdf) 23.
“Methyllithium Promoted Wittig Rearrangements of
alpha-Alkoxysilanes” Maleczka, R. E., Jr.; Geng,
F. Org.
Lett. 1999, 1, 1115–1118. (pdf) 24. “Stille
Couplings Catalytic in Tin — Beyond Proof
of Principle” Maleczka, R. E., Jr.; Gallagher, W.
P.; Terstiege, I. J. Am. Chem. Soc.
2000,
122,
384–385. (pdf) 25.
“Microwave Assisted One Pot
Hydrostannylation/Stille Couplings” Maleczka, R.
E., Jr.; Lavis, J. M.; Clark, D. H.; Gallagher, W.
P. Org. Lett.
2000,
2,
3655–3658. (pdf) 26.
“Stille Couplings Catalytic in Tin — The
'Sn–O' Approach” Gallagher, W. P.; Terstiege, I.;
Maleczka, R. E., Jr. J. Am. Chem. Soc.
2001,
123,
3194–3204. (pdf) 27.
“A Nozaki-Hiyama-Kishi (NHK) Coupling
Approach to the Phomactins” Mi, B.; Maleczka, R.
E., Jr. Org.
Lett. 2001,
3,
1491–1494. (pdf) 28.
“The Regiochemical Influence of
Oxo-Substitution in Palladium Mediated
Hydrostannations of 1-Alkynes” Rice, M. B.;
Whitehead, S. L.; Horvath, C. M.; Muchnij, J. A.;
Maleczka, R. E., Jr. Synthesis
2001,
1495–1504. (pdf) 29.
“Stille Couplings Catalytic in Tin: A
“Sn–F” Approach” Maleczka, R. E., Jr.;Gallagher,
W. P. Org.
Lett. 2001,
3,
4173–4176. (pdf) 30.
“Remarkably Selective Iridium Catalysts for
the Elaboration of Aromatic C–H Bonds” Cho, J.-Y.;
Tse, M. K.; Holmes, D.; Maleczka, R. E., Jr.;
Smith, M. R., III Science
2002,
295,
305–308. (pdf) 31.
“Total Synthesis of Proposed Amphidinolide
A via a Highly Selective Ring Closing Metathesis”
Maleczka, R. E., Jr.;Terrell, L. R.; Geng, F.;
Ward, J. S., III Org. Lett.
2002,
4,
2841–2844. (pdf) 32.
“Palladium Catalyzed Hydrodehalogenations
by Fluoride Activated Polymethylhydro-siloxane”
Maleczka, R. E., Jr.;Rahaim, R. J., Jr.; Teixeira,
R. R. Tetrahedron
Lett. 2002,
43,
7087–7090. (pdf) 33.
“Bleach/Acetic Acid Promoted Chlorinative
Ring Expansion of [2.2.1] and [2.2.2] Bicycles”
Ruggles, E. L.; Maleczka, R. E., Jr. Org. Lett.
2002,
4,
3899–3902. (pdf) 34.
“Room Temperature Dehalogenation of
Chloroarenes by Polymethylhydrosiloxane (PMHS)
under Palladium Catalysis” Rahaim, R. J., Jr.;
Maleczka, R. E., Jr. Tetrahedron Lett.
2002,
43,
8823–8826. (pdf) 35.
“Polymethylhydrosiloxane (PMHS) as an
Additive in Sonogashira Reactions” Gallagher, W.
P.; Maleczka, R. E., Jr. Synlett
2003,
537–541. (pdf) 36.
“C–H Activation/Borylation/Oxidation:
A One-Pot Unified Route To Meta-Substituted
Phenols Bearing Ortho/Para-Directing Groups”
Maleczka, R. E., Jr.; Shi, F.; Holmes, D.; Smith,
M. R., III J.
Am. Chem. Soc. 2003,
125,
7792–7793. (pdf) 37.
“PMHS Mediated Couplings of Alkynes or
Benzothiazoles with Various Electrophiles:
Application to the Synthesis of (–)-Akolactone A”
Gallagher, W. P.; Maleczka, R. E., Jr. J. Org. Chem.
2003,
68, 6775–6779.
(pdf) 38. “Stille
Reactions Catalytic in Tin: A “Sn-F” Route for
Intermolecular and Intramolecular Couplings”
Gallagher, W. P.; Maleczka, R. E., Jr. J. Org. Chem.
2005,
70,
841–846. (pdf) 39.
“A Toxicological Evaluation of Pyrene
Ozonation Byproducts:
Biphenyl-2,2',6,6'-tetracarb-aldehyde and
Biphenyl-2,2',6,6'-tetracarboxylic Acid”
Luster-Teasley, S. L.; Ganey, P. E.; DiOrio, M.;
Ward, J. S., III; Maleczka, R. E., Jr.; Trosko, J.
E.; Masten, S. J. Environ. Toxicol. Chem. 2005,
24,
733–740. (pdf) 40.
“Pd-Catalyzed Silicon Hydride Reductions of
Aromatic and Aliphatic Nitro Groups” Rahaim, R.
J., Jr.; Maleczka, R. E., Jr. Org. Lett.
2005,
7,
5087–5090. (pdf) 41.
“One-Pot Pd-Catalyzed
Hydrostannation/Stille Reaction with Acid
Chlorides as the Electrophiles” Lee, K.;
Gallagher, W. P.; Toskey, E. A.; Chong, W.;
Maleczka, R. E., Jr. J. Organomet. Chem.
2006,
691,
1462–1465. (pdf) 42.
“One-Pot Borylation/Amination Reactions:
Synthesis of Arylamine Boronate Esters from
Halogenated Arenes” Holmes, D.; Chotana, G. A.;
Maleczka, R. E., Jr.; Smith, M. R., III Org. Lett.
2006,
8,
1407–1410. (pdf)
43.
“Aromatic Borylation/Amidation/Oxidation: A
Rapid Route to 5-Substituted-3-amidophenols” Shi,
F.; Smith, M. R., III; Maleczka, R. E., Jr. Org. Lett.
2006,
8,
1411–1414. (pdf) 44.
“Pd(0)-Catalyzed PMHS Reductions of
Aromatic Acid Chlorides to Aldehydes” Lee, K.;
Maleczka, R. E., Jr. Org. Lett.
2006,
8,
1887–1888. (pdf) 45.
“-Substituted
Acylsilanes via a Highly Selective [1,4]-Wittig
Rearrangement of -Benzyloxyallylsilane”
Onyeozili, E. N.; Maleczka, R. E., Jr. Chem. Commun.
2006,
2466–2468. (pdf)
46.
“Studies on the Deprotonation and
Subsequent [1,4]-Wittig Rearrangement of -Benzyloxy-allylsilanes”
Onyeozili, E. N.; Maleczka, R. E., Jr. Tetrahedron Lett.
2006,
47,
6565–6568. (pdf) 47.
“Pd-Catalyzed Silane/Siloxane Reductions in
the One-Pot Conversion of Nitro Compounds to Their
Amines, Hydroxylamines, Amides, Sulfonamides, and
Carbamates” Rahaim, R. J., Jr.; Maleczka, R. E.,
Jr. Synthesis
2006,
3316–3340. (pdf) 48.
“Ir-Catalyzed Functionalization of
2-Substituted Indoles at the 7-Position:
Nitrogen-Directed Aromatic Borylation” Paul, S.;
Chotana, G. A.; Holmes, D.; Reichle, R. C.;
Maleczka, R. E., Jr.; Smith, M. R., III J. Am. Chem. Soc.
2006,
128,
15552–15553. (pdf) 49.
“Iridium-Catalyzed Borylation of
Thiophenes: Versatile, Synthetic Elaboration
Founded on Selective C–H Functionalization”
Chotana, G. A.; Kallepalli, V. A.; Maleczka, R.
E., Jr.; Smith, M. R., III Tetrahedron
2008,
64,
6103–6114. (pdf) 50.
“Aryl–Aryl Cross-Couplings that Avoid the
Preparation of Haloaromatics” Norberg, A. M.;
Sanchez, L.; Maleczka, R. E., Jr. Curr. Opin. Drug
Discov. Dev. 2008,
11,
853–869. (pdf) 51.
“Copper Puts Arenes in a Hard Position (A
Chemistry Perspective)” Maleczka, R. E., Jr. Science
2009,
323,
1572–1573. (pdf) 52.
“Reactions of vinyltributylgermanes and
aryl halides under Heck conditions” Torres, N. M.;
Lavis, J. M.; Maleczka, R. E., Jr. Tetrahedron Lett.
2009,
50,
4407–4410. (pdf) 53.
“Getting the Sterics Just Right: A
Five-Coordinate Iridium Trisboryl Complex that
Reacts with C—H Bonds at Room Temperature”
Chotana, G. A.; Vanchura, B. A., II; Tse, M. K.;
Staples, R. J.; Maleczka, R. E., Jr.; Smith, M.
R., III Chem. Commun. 2009, 5731–5733. (pdf) 54.
“Boc Groups as Protectors and Directors for
Ir-Catalyzed C–H Borylation of Heterocycles”
Kallepalli, V. A.; Shi, F.; Paul, S.; Onyeozili,
E. N.; Maleczka, R. E., Jr.; Smith, M. R., III J.
Org. Chem. 2009, 74,
9199–9201. (pdf)
55. “Divergent
Synthesis
of 2,3,5-Substituted Thiophenes by C–H
Activation/Borylation/Suzuki Coupling" Kallepalli,
V. A.; Sanchez, L.; Li, H.; Gesmundo, N. J.;
Turton, C. L.; Maleczka, R. E., Jr.; Smith, M. R.,
III Heterocycles 2010, 80,
1429–1448. (pdf)
56. “Enzymatic
Kinetic
Resolution of a-Hydroxysilanes” An, I.; Onyeozili,
E. N.; Maleczka, R. E., Jr. Tetrahedron:
Asymmetry 2010, 21, 527–534.
(pdf)
57.
“Electronic Effects in Iridium C–H
Borylations: Insights From Unencumbered Substrates
and Variation of Boryl Ligand Substituents”
Vanchura, B. A., II; Preshlock, S. M.; Roosen, P.
C. Kallepalli, V. A.; Staples, R. J.; Maleczka, R.
E., Jr.; Singleton, D. A.; Smith, M. R., III Chem.
Commun. 2010, 46, 7724–7726.
(pdf) 58.
“C–O Hydrogenolysis Catalyzed by Pd-PMHS
Nanoparticles in the Company of Chloroarenes”
Rahaim, R. J., Jr.; Maleczka, R. E., Jr. Org. Lett.
2011,
13,
584–587. (pdf)
59. “Practical
One-Pot C–H Activation/Borylation/Oxidation:
Preparation of 3-Bromo-5-Methylphenol on a
Multi-Gram Scale” Staples, R. J.; Smith, M. R.,
III; Maleczka, R. E., Jr. Synthesis 2011,
857–859. (pdf) 60.
“Ni, Co, & Mo-metal-catalyzed alkynes
hydrostannations using Bu3SnCl/PMHS/KF/18-crown-6
as an in situ Bu3SnH source” Ghosh, B.;
Maleczka, R. E., Jr. Tetrahedron Lett. 2011,
52, 5285–5287. (pdf) 61.
“Outer-Sphere Direction in Iridium C–H
Borylation” Roosen, P. C.; Kallepalli, V. A.;
Chattopadhyay, B.; Maleczka, R. E., Jr.;
Singleton, D. A; Smith, M. R., III J. Am.
Chem. Soc. 2012, 134,
11350–11353. (pdf)
62.
“[1,2]- and [1,4]-Wittig Rearrangements of
α-Alkoxysilanes: Effect of Substitutions at both
the Migrating Benzylic Carbon and the Terminal sp2
Carbon of the Allyl Moiety” Onyeozili, E. N.;
Mori-Quiroz, L. M.; Maleczka, R. E., Jr. Tetrahedron
2013, 69, 849–860. (pdf)
63.
“Non-Pd Transition Metal Catalyzed
Hydrostannations: Bu3SnF/PMHS as a Tin Hydride
Source” Ghosh, B.; Maleczka, R. E., Jr. Tetrahedron
2013, 69, 4000–4008. (pdf)
64. “High
Throughput Optimization of Ir-Catalyzed C–H
Borylation: A Tutorial for Practical Applications”
Preshlock, S. M.; Ghaffari, B.; Maligres, P. E.;
Krska, S. W.; Maleczka, Robert E.; Jr.; Smith, M.
R., III J. Am. Chem. Soc. 2013, 135,
7572–7582. (pdf)
65.
“A Traceless Directing Group for C–H
Borylation” Preshlock, S. M.; Plattner, D. L.;
Maligres, P. E.; Krska, S. W.; Maleczka, R. E.;
Jr.; Smith, M. R., III Angew. Chem. Int. Ed.
2013, 42, 12915– 12919. (pdf)
66.
“A One-Pot Allylation-Hydrostannation
Sequence with Recycling of the Intermediate Tin
Waste” Ghosh, B.; Amado-Sierra, M. R. I.; Holmes,
D.; Maleczka, R. E.; Jr. Org. Lett. 2014,
16, 2318–2321. (pdf)
67.
“Silyl Phosphorus and Nitrogen Donor
Chelates for Homogeneous Ortho Borylation
Catalysis” Ghaffari, B.; Preshlock, S. M.;
Plattner, D. L.; Staples, R. J.; Maligres, P. E.;
Krska, S. W.; Maleczka, R. E.; Jr.; Smith, M. R.,
III J. Am. Chem. Soc. 2014, 136,
14345–14348. (pdf)
68.
“A Catalytic Borylation / Dehalogenation
Route to ortho-Fluoro Arylboronates” Jayasundara,
C. R. K.; Unold, J. M.; Smith, M. R., III;
Maleczka, R. E.; Jr. Org. Lett. 2014,
16, 6072–6075. (pdf)
69.
“Stereoconvergent [1,2]- and [1,4]-Wittig
Rearrangements of
2-Silyl-6-aryl-5,6-dihydropyrans: A Tale of Steric
vs. Electronic Regiocontrol of Divergent Pathways”
Mori-Quiroz, L. M.; Maleczka, R. E., Jr. J.
Org. Chem. 2015, 80,
1163–1191. (pdf). 70.
“Harnessing C–H Borylation/Deborylation for
Selective Deuteration, Synthesis of Boronate
Esters, and Late Stage Functionalization”
Kallepalli, V. A.; Gore, K. A.; Shi, F.; Sanchez,
L.; Chotana, G. A.; Miller, S. L.; Maleczka, R.
E., Jr.; Smith, M. R., III J. Org. Chem. 2015,
80, 8341–8353. (pdf) 71.
“Reversible Borylene Formation from
Ring-Opening of Pinacolborane and Other
Intermediates Generated From 5-Coordinate
Trisboryl Complexes: Implications for Catalytic
C–H Borylation” Ghaffari, B.; Vanchura, B. A., II;
Chotana, G. A.; Staples, R. J.; Holmes, D.;
Maleczka, R. E., Jr.; Smith, M. R., III Organometallics
2015, 34, 4732–4740. (pdf)
72. “Bismuth
Acetate as a Catalysts for the Sequential
Protodeboronation of Di- and Triborylated Indoles”
Shen, F.; Tyagarajan, S.; Perera, D.; Krska, S.
W.; Maligres, P. E.; Smith, M. R., III;
Maleczka, R. E., Jr. Org. Lett. 2016,
18, 1554–1557. (pdf) 73.
“Improved Synthesis of Electron Deficient
Bipyridines” Li, H.; Oppenheimer, J.; Smith,
M. R., III; Maleczka, R. E., Jr. Tetrahedron
Lett. 2016, 57, 2231–2232. (pdf)
74. “Ir-Catalyzed
ortho-Borylation of Phenols Directed
by Substrate-Ligand Electrostatic
Interactions: A Combined
Experimental / in
Silico Strategy for Optimizing
Weak Interactions” Chattopadhyay, B.; Dannatt, J. E.; Andujar-De
Sanctis, I.
L.; Gore, K. A.; Maleczka, R. E.;
Jr.; Singleton, D. A.;
Smith, M. R., III J. Am. Chem. Soc. 2017, 139, 7864–7871.
(pdf) 75. “Achieving
High Ortho Selectivity in
Aniline C-H Borylations by
Modifying Boron Substituents”
Smith, M. R., III; Bisht, R.;
Haldar, C.; Pandey, G.; Dannatt,
J. E.; Ghaffari, B.; Maleczka, R.
E.; Jr.; Chattopadhyay,
B. ACS
Catal. 2018,
8,
6216–6223.
(pdf) 76. “Cobalt-Catalyzed
C-H Borylation
of Alkyl
Arenes and
Heteroarenes
Including the
First
Selective
Borylations of
Secondary
Benzylic C–H
Bonds”
Jayasundara, C. R.
K.; Sabasovs,
D.; Staples,
R. J.;
Oppenheimer,
J.; Smith, M. R., III Maleczka, R. E., Jr. Organometallics 2018, 37,
1567–1574. (pdf)
77. “Separation of Asymmetrically Capped
Double-Decker
Silsesquioxanes
Mixtures” Vogelsang, D.
F.; Dannatt, J. E.;
Maleczka, R. E., Jr.;
Lee, A. Polyhedron
2018,
155, 189–193. (pdf) 78. “HPLC Characterization of cis and trans Mixtures
of Double-Decker Shaped Silsesquioxanes” Vogelsang, D. F.; Maleczka,
R. E., Jr.; Lee, A. Silicon 2019, 11, 5–13. (pdf) 79. “Predictive Liquid Chromatography Separation for Mixtures of Functionalized Double-decker Shaped Silsesquioxanes Based on HPLC Chromatograms” Vogelsang, D. F.; Maleczka, R. E., Jr.; Lee, A. Ind. Eng. Chem. Res. 2019, 58, 403–410. (pdf) 80. “Phase Behavior of cis–trans Mixtures of Double-Decker Shaped Silsesquioxanes for Processability Enhancement” Vogelsang, D. F.; Dannatt, J. E.; Shoen, B. W.; Maleczka, R. E., Jr.; Lee, A. ACS Appl. Nano Mater. 2019, 2, 1223–1231. (pdf) 81. “A General Diversity Oriented Synthesis of Asymmetric Double-Decker Shaped Silsesquioxanes” Barry, B.-D.; Dannatt, J. E.; King, A. K.; Lee, A.; Maleczka, R. E., Jr. Chem. Commun. 2019, 55, 8623–8626. (pdf) 82. “C–H Borylation Catalysts that Distinguish Between Similarly Sized Substituents Like Fluorine and Hydrogen” Miller, S. L.; Chotana, G. A.; Fritz, J. A.; Chattopadhyay, B.; Maleczka, R. E., Jr.; Smith, M. R., III Org. Lett. 2019, 21, 6388–6392. (pdf) 83. “Para-Selective, Iridium-Catalyzed C–H Borylations of Sulfated Phenols, Benzyl Alcohols, and Anilines Directed by Ion-Pair Electrostatic Interactions” Montero Bastidas, J. R.; Oleskey, T. J.; Miller, S. L.; Smith, M. R., III; Maleczka, R. E., Jr. J. Am. Chem. Soc. 2019, 141, 15483–15487. (pdf) 84. “One-Pot Iridium-Catalyzed C–H Borylation / Sonogashira Cross-Coupling: Access to Borylated Aryl Alkynes” Chotana, G. A.; Montero Bastidas, J. R.; Miller, S. L.; Smith, M. R., III; Maleczka, R. E., Jr. Molecules 2020, 25, 1754–1766. (pdf) 85. “Silylcyclopropanes by Selective [1,4]-Wittig Rearrangement of 4-Silyl-5,6-dihydropyrans” Mori-Quiroz, L. M.; Maloba, E. W.; Maleczka, R. E., Jr. Org. Lett. 2021, 23, 5724–5728. (pdf) 86. “Phase
behavior
of selected condensed double-decker shaped
silsesquioxane compounds”
Vogelsang, D.
F.; Maleczka, R. E., Jr.; Lee, A. Silicon.
2021, 13, published on-line
11/4/2021. (pdf) 87. “Amide Directed Iridium C(sp3)–H
Borylation Catalysis with High N-Methyl
Selectivity” Dannatt, J. E.;
Yadav, A.; Smith, M. R., III; Maleczka, R. E.;
Jr. Tetrahedron 2022, 109, 132578. (pdf) 88. “Merging
Iridium-Catalyzed
C–H Borylations with Palladium-Catalyzed
Cross-Couplings using Triorganoindium Reagents” Jayasundara, C. R. K.; Gil-Negrete,
J.-M.; Montero Bastidas, J. R.; Martínez,
M. M.;
Sestelo, J. P.; Smith, M. R., III; Maleczka, R. E.; Jr.
J. Org. Chem. 2022, 86, 751–759. (pdf) 89. “Steric shielding effects
induced by intramolecular C–H•••O hydrogen bonding: remote
borylation directed by Bpin groups” Montero Bastidas, J. R.;
Chhabra, A.; Feng, Y.; Oleskey, T. J.; Smith, M. R.,
III; Maleczka, R. E.; Jr.
ACS Catal. 2022, 12, 2694–2705. (pdf) Book Chapters 1.
“Advances in the Total Synthesis of
Amphidinolide A” Maleczka, R. E., Jr.;
Terrell, L. R. In Natural
Product Chemistry at the Turn of the
Century; Rahman, A.-u.;
Choudhary, M. I.; Khan, K. M., Eds.; Print
Arts: Karachi 2002; pp. 105–114. 2.
“Polymethylhydrosiloxane (PMHS)”
Lavis, J. M.; Maleczka, R. E., Jr. In eEROS–Electronic
Encyclopedia of Reagents for Organic
Synthesis (DOI:
10.1002/047084289X); Paquette, L. A.; Crich,
D.; Fuchs, P. L.; Wipf, P., Eds.; Wiley: New
York; Published online April 15, 2003, http://onlinelibrary.wiley.com/o/eros/articles/rn00062/frame.html.
(pdf) 3. “(R)-(–)-2,2-Diphenylcyclopentanol”
Onyeozili,
E. N.; Maleczka, R. E., Jr. In eEROS–
Electronic Encyclopedia of Reagents for
Organic Synthesis (DOI:
10.1002/047084289X); Paquette, L. A.; Crich,
D.; Fuchs, P. L.; Wipf, P., Eds.; Wiley: New
York, Published online April 15, 2003, http://onlinelibrary.wiley.com/o/eros/articles/rn00225/frame.html.
(pdf) 4.
“(4S,5S)-2-Bromo-1,3-bis[(4-methylphenylsulfonyl]-4,5-diphenyl-1,3,2-diazaborolidine”
Pellerito,
A. M.; Maleczka, R. E., Jr. In eEROS–Electronic
Encyclopedia of Reagents for Organic
Synthesis (DOI:
10.1002/047084289X); Paquette, L. A.; Crich,
D.; Fuchs, P. L.; Wipf, P., Eds.; Wiley: New
York, Published online October 15, 2003, 5.
“Triethylsilane (First Update)”
Rahaim, R. J., Jr.; Maleczka, R. E., Jr. In
eEROS–Electronic
Encyclopedia of Reagents for Organic
Synthesis (DOI:
10.1002/047084289X); Paquette, L. A.; Crich,
D.; Fuchs, P. L.; Molander, G. A., Eds.;
Wiley: New York; Published online March 17,
2007,
http://onlinelibrary.wiley.com/o/eros/articles/rt226/frame.html.
(pdf) 6.
“Triphenylsilane (First Update)”
Torres, N. M.; Maleczka, R. E., Jr. In eEROS–Electronic
Encyclopedia of Reagents for Organic
Synthesis (DOI:
10.1002/047084289X); Paquette, L. A.; Crich,
D.; Fuchs, P. L.; Molander, G. A., Eds.;
Wiley: New York; Published online March 17,
2007,
http://onlinelibrary.wiley.com/o/eros/articles/rt385/frame.html.
(pdf) 7. “Trimethylene
Oxide
(First Update)” Muchnij, J. A.; Maleczka, R.
E., Jr. In eEROS–
Electronic Encyclopedia of Reagents for
Organic Synthesis (DOI:
10.1002/047084289X); Paquette, L. A.; Crich,
D.; Fuchs, P. L.; Molander, G. A., Eds.;
Wiley: New York; Published online September
17, 2007,
http://onlinelibrary.wiley.com/o/eros/articles/rt273/frame.html.
(pdf) 8.
“Bismuth Pentafluoride” Kim S.-H.;
Maleczka, R. E., Jr. In eEROS–Electronic
Encyclopedia of Reagents for Organic
Synthesis (DOI:
10.1002/047084289X); Paquette, L. A.; Crich,
D.; Fuchs, P. L.; Molander, G. A., Eds.;
Wiley: New York; Published online September
17, 2007,
http://onlinelibrary.wiley.com/o/eros/articles/rn00735/frame.html.
(pdf) 9.
“1-Chloromethyl-4-fluoro-1,4-diazoniabicyclo[2.2.2]octane
Bis(tetrafluoroborate)
(First Update)” An, I.; Maleczka, R. E., Jr.
In eEROS–Electronic
Encyclopedia of Reagents for Organic
Synthesis (DOI:
10.1002/047084289X); Paquette, L. A.; Crich,
D.; Fuchs, P. L.; Molander, G. A., Eds.;
Wiley: New York; Published online September
17, 2007, 10. “Chlorotrimethylstannane
(First
Update)” Lee, K.; Maleczka, R. E., Jr. In eEROS–Electronic
Encyclopedia of Reagents for Organic
Synthesis (DOI:
10.1002/047084289X); Paquette, L. A.; Crich,
D.; Fuchs, P. L.; Molander, G. A., Eds.;
Wiley: New York; Published online September
17, 2007,
http://onlinelibrary.wiley.com/o/eros/articles/rc160/frame.html.
(pdf) 11. “Catalytic Hydrodehalogenation Reactions” Ghosh, B.; Maleczka, R. E., Jr. In Science of Synthesis: Catalytic Reduction in Organic Synthesis Vol. 1 (DOI 10.1055/b-005-145236); de Vries, J. G., Ed.; Georg Thieme Verlag KG: Stuttgart 2018; pp. 355–373.
Patents 1.
“Processes and Intermediates for
Preparing Macrocycles” Smith, A. B., III;
Condon, S. M.; Leahy, J. W.; Leazer, J. L.,
Jr.; Maleczka, R. E., Jr.; McCauley, J.
A. U.S. Patent 5,621,108; April 15,
1997. (pdf) 2.
“Process for the Synthesis of Phenols
from Arenes” Maleczka, R. E., Jr.; Smith, M.
R., III; Holmes, D.; Shi, F. U.S.
Patent 6,828,466; December 7, 2004. (pdf) 3.
“Process for the Catalytic Synthesis
of Biaryls and Polymers from Aryl Compounds”
Smith, M. R., III; Maleczka, R. E., Jr. U.S.
Patent 6,867,302; March 15, 2005. (pdf) 4. “Synthesis
of Aminoboronic Esters and Substituted
Anilines from Arenes via Catalytic C–H
Activation/Borylation/Amination and Uses
Thereof” Maleczka, R. E., Jr.; Smith, M. R.,
III; Holmes, D. U.S. Patent 6,958,196;
October 25, 2005. (pdf) 5.
“Process for the Catalytic Synthesis
of Biaryls and Polymers from Aryl Compounds”
Smith, M. R., III; Maleczka, R. E., Jr. U.S.
Patent 7,148,356; December 12, 2006. (pdf) 6.
“Process for the Preparation of a
Borylated Thiophene” Smith, M. R.,
III; Maleczka, R. E., Jr.; Chotana, G. A.;
Kallepalli, V.; Paul, S. U.S. Patent
Application 2008-0091035; April 17, 2008. (pdf) 7.
“Process for Producing N-Protected
Boryl Compounds” Smith, M. R., III;
Maleczka, R. E., Jr.; Kallepalli, V.;
Onyeozili, E. U.S. Patent Application
2008-0146814; June 19, 2008. (pdf) 8.
“Process for the Preparation of
2-Substituted-7-Boryl Indoles and Compounds”
Smith, M. R., III; Maleczka, R. E., Jr.;
Chotana, G. A.; Paul, S. U.S. Patent
Application 2008-0167476; July 10, 2008. (pdf) 9.
“Process for Producing Cyano Substituted
Arene Boranes and Compounds” Smith, M. R.,
III; Maleczka, R. E., Jr.; Chotana, G. A.
U.S. Patent 7,514,563; April 7, 2009. (pdf) 10. “Process
for Producing Oxazole, Imidazole, Pyrrazole
Boryl Compounds” Smith, M. R., III;
Maleczka, R. E., Jr.; Kallepalli, V.;
Onyeozili, E. U.S. Patent 7,709,654; May 4,
2010. (pdf) 11. “Methods
for Producing Borylated Arenes” Smith, M.
R., III; Maleczka, R. E., Jr.; Li, H.;
Jayasundara, C.; Oppenheimer, J.; Sabasovs,
D. U.S. Patent Application No. 20150065743;
March 5, 2015. (pdf) 12. “Methods
for Producing Borylated Arenes” Smith, M.
R., III; Maleczka, R. E., Jr.; Sabasovs, D.;
Oppenheimer, J. U.S. Patent Application
20150361109; December
17,
2015. (pdf)
13. “Synthetic
Methods for Forming Saturated
(Hetero)cyclic Borylated
Hydrocarbons and Related Compounds” Smith, M.
R., III; Shannon, T. M.; Maleczka,
R. E., Jr.; Fornwald, R. M. U.S.
Patent Application 20180051042;
February 22, 2018. (pdf) 14. “Synthetic Methods for Diboron Reagents and Related Compounds Arenes” Smith, M. R., III; Maleczka, R. E., Jr. U.S. Patent 10,077,278; September 18, 2018. 15. “Methods for Producing Borylated Arenes” Smith, M. R.; Maleczka, R. E.; Li, H.; Jayasundara, C. R. K.; Oppenheimer, J.; Sabasovs, D. U.S. Patent 10,112,960; October 30, 2018. 16. “Methods for Producing Borylated Arenes” Smith, M. R., III; Maleczka, R. E., Jr.; Sabasovs, D.; Oppenheimer, J. U.S. Patent 10,166,533; January 1, 2019. 17. “Methods for Producing Borylated Arenes” Smith, M. R.; Maleczka, R. E.; Li, H.; Jayasundara, C. R. K.; Oppenheimer, J.; Sabasovs, D. U.S. Patent Application 201900620350; February 28, 2019.
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