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Borhan Group Publications

(Publication List Without Graphics)

          

 

Science 2012

OrgLett 2017, 19, 1722-1725

 

 

Computationally Aided Absolute Stereochemical Determination of Asymmetric Sulfoxides via Central to Axial Induction of Chirality

 

Gholami, H.; Zhang, J.; Anyika, M.; Borhan, B.

 

Science, 2

 

 

Science 2012

OrgLett 2017, 19, 1362-1365

 

 

Computationally Aided Absolute Stereochemical Determination of Enantioenriched Amines

 

Zhang, J.; Gholami, H.; Ding, X.; Chun, M.; Vasileiou, C.; Nehira, T.; Borhan, B.

 

Science, 2

 

 

Science 2012

JACS 2017, 139, 2132-2135

 

Highly Regio- and Enantioselective Vicinal Dihalogenation of Allyl Amides

 

Soltanzadeh, B.; Jaganathan, A.; Yi, Y.; Yi, H.; Staples, R. J.; Borhan, B.

 

Science, 2

 

Science 2012

Structure 2016, 24, 1590-1598

 

Domain-Swapped Dimers of Intracellular Lipid-Binding Proteins: Evidence for Ordered Folding Intermediates

Assar, Z.; Nossoni, Z.; Wang, W.; Santos, E. M.; Kramer, K.; McCormack, C.; Vasileiou, C.; Borhan, B.; Geiger, J. H.

Science, 2

 

Science 2012

Org. Lett. 2016, 18, 3976-3979.

 

Mechanistically Inspired Route toward Hexahydro-2H-chromenes via Consecutive [4 + 2] Cycloadditions

Ashtekar, K. D.; Ding, X.; Toma, E.; Sheng, W.; Gholami, H.; Rahn, C.; Reed, P.; Borhan, B.

Science, 2

 

Science 2012

J. Am. Chem. Soc. 2016, 138, 8802-8808.

 

A Photoisomerizing Rhodopsin Mimic Observed at Atomic Resolution

Nosrati, M.; Berbasova, T.; Vasileiou, C.; Borhan, B.; Geiger, J. H.

Science, 2

 

Science 2012

J. Am. Chem. Soc. 2016, 138, 8114-8119.

 

Nucleophile-Assisted Alkene Activation: Olefins Alone Are Often Incompetent

Ashtekar, K. D.; Vetticatt, M.; Yousefi, R.; Jackson, J. E.; Borhan, B.

Science, 2

 

Science 2012

ChemEuropJ 2016, 22, 9235-9239

 

Host-Guest Assembly of a Molecular Reporter with Chiral Cyanohydrins for Assignment of Absolute Stereochemistry

Gholami, H.; Anyika, M.; Zhang, J.; Vasileiou, C.; Borhan, B.

Science, 2

 

Science 2012

ChemBioChem 2016, 17, 407-414

 

Light-Activated Reversible Imine Isomerization: Towards a Photochromic Protein Switch

Berbasova, T.; Santos, E. M.; Nosrati, M.; Vasileiou, C.; Geiger, J. H.; Borhan, B.

Science, 2

 

Science 2012

Angew. Chem. Int. Ed. Engl. 2015, 54, 9517-9522

 

Highly Stereoselective Intermolecular Haloetherification and Haloesterification of Allyl Amides

Soltanzadeh, B.; Jaganathan, A.; Staples, R. J. ; Borhan, B.

Science, 2

 

Science 2012

Angew. Chem. Int. Ed. Engl. 2015, 54, 4274-4278

 

Sensing Remote Chirality: Stereochemical Determination of beta-, gamma-, and delta-Chiral Carboxylic Acids

Tanasova, M.; Anyika, M.; Borhan, B.

Science, 2

 

Science 2012

J. Am. Chem. Soc. 2015, 137, 1073-1080.

 

"Turn-On" Protein Fluorescence: In Situ Formation of Cyanine Dyes

Yapici, I.; Lee, K. S. S.; Berbasova, T.; Nosrati. M.; Jia, X.; Vasileiou, C.; Santos, E. M.; Geiger, J. H.; Borhan, B.

Science, 2

 

Science 2012

Act. Cryst. Sec. D-Biol. Cryst. 2014, 70, 3226-3232

 

Structures of Holo Wild-Type human Cellular Retinol Binding Protein II (hCRBPII) Bound to Retinol and Retinal

Nossoni, Z.; Assar, Z.; Yapici, I.; Nosrati, M.; Wang, W.; Berbasova, T.; Vasileiou, C.; Borhan, B.; Geiger, J. H.

Science, 2

 

Science 2012

J. Am. Chem. Soc. 2014, 136, 13355-13362.

 

A New Tool to Guide Halofunctionalization reactions: The Halenium Affinityu (HalA) Scale

Ashtekar, K. D.; Marzijarani Salehi, N.; Jaganathan, A.; Holmes, D.; Jackson, J. E.;

Borhan, B.

Science, 2

 

 

Science 2012

Org. Lett. 2014, 16, 3616-3619.

 

Chlorosulfonamide Salts are Superior Electrophilic Chlorine Precursors for the Organocatalytic Asymmetric Chlorocyclization of Unsaturated Amides

Jaganathan, A.; Borhan, B.

Science, 2

 

 

Science 2012

J. Am. Chem. Soc. 2014, 136, 550-553.

 

Point-to-Axial Chirality Transfer—A New Probe for "Sensing" the Absolute Configurations of Monoamines

Anyika, M.; Gholami, H.; Ashtekar, K. D.; Acho, R.; Borhan, B.

Science, 2

 

 

Science 2012

J. Am. Chem. Soc. Mass Spec. 2014, 25, 141-148

 

Quantification of Competing H3PO4 vs HPO3 + H2O Neutral Losses from Regioselective 18O-Labeled Phosphopeptides

Cui, L.; Yapici, I.; Borhan, B.; Reid, G. E.

Science, 2

 

 

Science 2012

BioEssays. 2014, 36, 65-74

 

The Photochemical Determinants of Color Vision

Wang, W.; Geiger, J. H.; Borhan, B.

Science, 2

 

 

Science 2012

Tetrahedron 2013, 69, 9469-9474

 

7-beta- and 10-beta-Hydroxylated congeners of CAF-603; elucidation of absolute configuration of CAF-603 family, and their SAR studies in the anti-fungal activity

Yasamura, R.; Ashtekar, K. D.; Tonouchi, A.; Nehira, T.; Borhan, B.; Hashimoto, M.

Science, 2

 

 

Science 2012

J. Am. Chem. Soc. 2013, 135, 16111-16119

 

Rational Design of a Colorimetric pH Sensor from a Soluble Retinoic Acid Chaperone

Berbasova, T.; Nosrati, M.; Vasileiou, C.; Wang, W.; Lee, K. S. S.; Yapici, I.; Geiger, J. H.; Borhan, B.

Science, 2

 

 

Science 2012

J. Am. Chem. Soc. 2013, 135, 14524-14527

 

Dissecting the Stereocontrol Elements of a Catalytic Asummetric Chlorolactonization: Syn Addition Obviates Bridging Chloronium

Yousefi, R.; Ashtekar, K. D.; Whitehead, D. C.; Jackson, J. E.; Borhan, B.

Science, 2

 

 

Science 2012

J. Am. Chem. Soc. 2013, 135, 14806-14813

 

Kinetic Resolution of Unsaturated Amides in a Chlorocyclization Reaction: Concomitant Enantiomer Differentiation and Face Selective Alkene Chlorination by a Single Catalyst

Jaganathan, A.; Staples, R. J.; Borhan, B.

Science, 2

 

 

Science 2012

J. Phys. Chem. B 2013, 117, 10053-10070

Toward an Understanding of the Retinal Chromophore in Rhodopsin Mimics

Huntress, M. M.; Gozem, S.; Malley, K. R.; Jailaubekov, A. E.; Vasileiou, C.; Vengris, M.; Geiger, J. H.; Borhan, B.; Shapiro, I.; Larsen, D. S.; Olivucci, M.

Science, 2

 

 

Science 2012

Chem. Europ. J. 2013, 19, 9015-9021

 

Solvent-Dependent Enantiodivergence in the Chlorocyclization of Unsaturated Carbamates

Garzan, A.; Jaganathan, A.; Salehi-Marzijarani, N.; Yousefi, R.; Whitehead, D. C.; Jackson, J. E.; Borhan, B.

Science, 2

 

Science 2012

Science 2012, 338, 1340-1343

 

Tuning the Electronic Absorption of Protein-Embedded All-trans-Retinal

Wang, W.; Nossoni, Z.; Berbasova, T.; Watson, C.; Yapici, I.; Lee, K. S. S.; Vasileiou, C.; Geiger, J. H.; Borhan, B.

Science, 2

 

JMolMod

 

J. Mol. Mod.2012, 18, 4547-4556

 

Selectivity of Labeled Bromoethylamine for Protein Alkylation

Marincean, S.; Rabago-Smith, M.; Beltz, L.; Borhan, B.

JMolMod

 

OrgLett.jpg

 

Org. Lett. 2012, 14, 3592-3595

 

3,4-Dihydroxypyrrolidines via Modified Tandem Aza-Payne/Hydroamination Pathway

Kulshrestha, A.; Salehi-Marzijarani, N.; Ashtekar, K. D.; Staples, R.; Borhan, B.

 

 

OrgLett

 

JACS.jpg

 

JACS 2012, 134, 9026-9029

 

 

Absolute Configuration of 1,n-Glycols: A Nonempirical Approach to

Long-Range Stereochemical Determination

Li, X.; Burrell, C.; Staples, R.; Borhan, B.

 

OrgLett

 

 

EJOC.gif

 

Eur. J. Org. Chem. 2012, 12,

3261-9029

 

 

Conformational Preference in Bis(porphyrin) Tweezer Complexes: A Versatile Chirality Sensor for Chiral Carboxylic Acids

Tanasova, M.; Borhan, B.

 

EJOC

 

 

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ChemPlusChem. 2012, 77, 273-276

 

 

Probing Wavelength Regulation with an Engineered Rhodopsin Mimic and a C-15-Retinal Analogue

Lee, K. S. S; Berbasova, T.; Vasileiou, C.; Jia, X.; Wang, W.; Choi, Y.; Nossoni, F.;

Geiger, J. H.; Borhan, B.

 

EJOC

 

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OrgLett 2011, 13, 5732-5735

 

Development of a Formal Catalytic Asymmetric [4+2] Addition of Ethyl-2,3-butadienoate with Acyclic Enones

Ashtekar, K. D.; Staples, R. J.; Borhan, B.

 

EJOC

 

 

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Chem. Europ. J. 2011, 17,

12326-12339

 

Selectivity in the Addition Reactions of Organometallic Reagents to Aziridine-2-carboxaldehydes: The Effects of Protecting Groups and Substitution Patterns

Kulshrestha, A.; Schomaker, J. M.; Holmes, D.; Staples, R. J.; Jackson, J. E.; Borhan, B.

 

EJOC

 

 

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Org. Biomol. Chem. 2011, 9,

4741-4744

 

Catalytic Oxidative Cleavage of Olefins Promoted by Osmium Tetroxide and Hydrogen Peroxide

Hart, S. R.; Whitehead, D. C.; Travis, B.; Borhan, B.

 

EJOC

 

 

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Tet. Lett. 2011, 52, 2288-2291

 

A Peptide Bromoiodinane Approach to Asymmetric Bromolactonization

Whitehead, D. C.; Fhaner, M.; Borhan, B.

 

EJOC

 

 

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Ang. Chem. Int. Ed. 2011, 50,

2593-2596

 

A Catalytic Asymmetric Chlorocyclization of Unsaturated Amides

Jaganathan, A.; Garzan, A.; Whitehead, D. C.; Staples, R. J.; Borhan, B.

 

EJOC

 

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Org. Lett. 2011, 13, 608-611

 

On the Chlorenium Source in the Asymmetric Chlorolactonization Reaction

Yousefi, R.; Whitehead, D. C.; Mueller, J. M.; Staples, R. J.; Borhan, B.

 

EJOC

 

 

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Chem. Eur. J. 2010, 16,

13749-13756

A Minimalist Approach for the Structural Revision of Mucoxin

Yan, J.; Garzan, A.; Narayan, R.; Vasileiou, C.; Borhan, B.

 

EJOC

 

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FASEB J. 2010, 24, 5033-5042

 

Regulation of Intermediary Metabolism by the PKC Delta Signalosome in Mitochondria

Acin-Perez, R.; Hoyos, B.; Gong, J. L.; Vinogradov, V.; Fischman, D. A. Leitges, M.; Borhan, B.; Starkov, A.; Manfredi, G.; Hammerling, U.

 

EJOC

 

 

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J. Am. Soc. Mass. Spec. 2010, 21,

1339-1351

 

 

"Fixed Charge" Chemical Derivatization and Data Dependant Multistage Tandem Mass Spectrometry for Mapping Protein Surface Residue Accessibility

Zhou, X.; Lu, Y.; Wamg, W.; Borhan, B.; Reid, G. E.

 

EJOC

 

 

TetLett.gif

 

Microbiology-SGM 2010, 156,

1589-1599

 

The Antimicrobial Compound Reuterin (3-Hydroxypropion Aldehyde) Includes Oxidative Stress via Interaction with Thiol Groups

Schaefer, L.; Auchtung, T. A.; Hermans, K. E.; Whitehead, D.; Borhan, B.; Britton, R. A.

 

EJOC

 

 

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J. Am. Chem. Soc 2010, 132,

4490-4499

 

Magnetic Glyco-Nanoparticles: A Tool to Detect, Differentiate and Unlock the Glyco-codes of Cancer via Magnetic Resonance Imaging

El-Boubbou, K.; Zhi, D. C.; Vasileiou, C.; Borhan, B.; Davide, P.; Wei, L.; Huang, X.

 

EJOC

 

 

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J. Am. Chem. Soc. 2010, 132,

3298-3300

An Organocatalytic Asymmetric Chlorolactonization

Whitehead, D. C.; Yousefi, R.; Jaganathan, A.; Borhan, B.

 

EJOC

 

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Proteins: Structure, Function and Bioinformatics 2009, 77, 812-822

 

Elucidating the Exact Role of Engineered CRABPII residues for the Formation of a Retinal Protonated Schiff Base

Vasileiou, C.; Wang, W.; Jia, X.; Lee, K. S. S.; Watson, C.; Geiger, J. H.; Borhan, B.

 

EJOC

 

 

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Eur. J. Org. Chem. 2009, 25, 4242-4253

 

An Unusual Conformation of alpha-Haloamides due to Coperative Binding With Zincated Porphyrins

Tanasova, M.; Tang, Q.; Olmsted, C. C.; Vasileiou, C.; Li, X.; Anyika, M.; Borhan, B.

 

EJOC

 

 

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Proteins: Structure, Function and Bioinformatics 2009, 76, 281-290

 

Dissection of the Critical Binding Determinants of Cellular Retinoic Acid Binding Protein II by Mutagenesis and Fluorescence Quenching

Vasileiou, C.; Wang, W.; Jia, X.; Lee, K. S. S.; Watson, C.; Geiger, J. H.; Borhan, B.

 

EJOC

 

 

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Tet. Lett. 2009, 50, 656-658

A simple and Expedient Method for the Preparation of N-Chlorohydantoins

Whitehead, D. C.; Staples, R. J.; Borhan, B.

 

EJOC

 

 

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Chirality 2009, 21, 374-382

 

Enhancement of Exciton Coupled Circular Dichroism with Sterically Encumbered Bis-Porphyrin Tweezers

Tanasova, M.; Vasileiou, C.; Olumolade, O. O.; Borhan, B.

 

EJOC

 

 

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Anal. Chem. 2008, 80, 9279-9287

 

Ionic Reagent for Controlling the Gas-Phase Fragmentation Reactions of Cross-Linked Peptides

Lu, Y. L.; Tanasova, M.; Borhan, B.; Reid, G. E.

 

EJOC

 

 

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J. Am. Chem. Soc. 2008, 130, 16126-16127

 

Prompt Determination of Absolute Configuration for Epoxy Alcohols via Exciton Chirality Protocol

Li, X.; Borhan, B.

 

EJOC

 

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Act. Cryst. Sec. D-Biol. Cryst. 2008, 64, 1228-1239

 

Structural Analysis of Site-Directed Mutants of Cellular Retinoic Acid Binding Protein II Addresses the Relationship Between Structural Integrity and Ligand Binding

Vaezeslami, S.; Jia, X.; Vasileiou, C.; Borhan, B.; Geiger, J. H.

 

EJOC

 

 

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J. Am. Chem. Soc. 2008, 130, 12228-12229

 

Total Synthesis of Haterumalides NA and NC via a CHromium-Mediated Macrocyclization

Schomaker, J. M.; Borhan, B.

 

EJOC

 

 

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J. Am. Chem. Soc. 2008, 130, 1885-1893

 

Fluorinated Porphyrin Tweezer: A Powerful Reporter of Absolute Configuration for Erythro and Threo Diols, Amino Alcohols and Diamines

Li, X.; Tanasova, M.; Vasileiou, C.; Borhan, B.

 

EJOC

 

 

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J. Am. Chem. Soc. 2007, 129, 6140-6148

 

Protein Design: Reengineering Cellular Retinoic Acid Binding Protein II into a Rhodopsin Protein Mimic

Vasileiou, C.; Vaezeslami, S.; Crist, R. M.; Rabago-Smith, M.; Geiger, J.; Borhan, B.

 

EJOC

 

 

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J. Am. Chem. Soc. 2007, 129, 3794-3795

 

Tetrasubstituted Pyrrolidines via a Substituted Aza-Payne/Hydroamination Reaction

Schomaker, J. M.; Geiser, A. R.; Huang, R; Borhan, B.

 

EJOC

 

 

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J. Am. Chem. Soc. 2007, 129, 1996-2003

 

Diastereomerically and Enantiomerically Pure 2,3-Disubstituted Pyrrolidines from 2,3-aziridin-1-ols using a Sulfoxonium Ylide: A One-Carbon Homologative Relay Ring Expansion

Schomaker, J. M.; Bhattacharrjee, S.; Yan, J.; Borhan, B.

 

EJOC

 

 

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J. Mol. Biol. 2006, 363, 687-701

 

 

The Structure of Apo-Wild Type Cellular Retinoic Acid Binding Protein II at 1.4 A and its Relationship to Ligand Binding and Nuclear Translocation

Vaezaslami, S.; Mathes, E.; Vasileiou, C.; Borhan, B.; Geiger, J. H.

 

EJOC

 

 

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Tet. Lett.. 2006, 47, 3797-3800

 

The OsO4-Mediated Oxidative Cleavage of Olefins Catalyzed by Alternative Osmium Sources

Whitehead, D. C.; Travis, B. R.; Borhan, B.

 

EJOC

 

 

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J. Am. Chem. Soc. 2006, 128, 4522-4523

 

Engineering a Rhodopsin Protein Mimic

Crust, R. M.; Vasileiou, C.; Rabago-Smith, M.; Geiger, J. H.; Borhan, B.

 

EJOC

 

 

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Chirality 2006, 18, 72-83

 

Circular Dichroism of Heterochromophoric and Partially Regenerated Purple Membrane: Search for Exciton Coupling

Karnaukhova, E.; Vasileiou, C.; Wang, A.; Berova, N.; Nakanishi, K.; Borhan, B.

 

EJOC

 

 

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J. Org. Chem. 2006, 71, 1416-1429

 

Synthesis of the Proposed Structure of Mucoxin via Regio- and Stereoselective Tetrahydrofuran Ring-Forming Strategies

Narayan, R. S.; Borhan, B.

 

EJOC

 

 

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J. Gen. Physiol. 2005, 126, 453-460

 

 

Defining the Retinoid Binding Site in the Rod Cyclic Nucleotide-Gated Channel

Horrigan, D. M.; Tetreault, M. L.; Tsomaia, N.; Vasileiou, C.; Borhan, B.; Mierke, D. F.; Crouch, R. K.; Zimmerman, A. L.

 

EJOC

 

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Tet. Lett. 2005, 46, 6737-6740

 

 

Polymer-Supported Synthesis of Mono-Substituted Porphyrins

Yang, Q.; Streb, K. K.; Borhan, B.

 

EJOC

 

 

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J. Am. Chem. Soc. 2005, 127, 6946-6947

 

 

One-Pot Regio- and Stereoselective Cyclization of 1,2,n-triols

Zheng, T.; Narayan, R. S.; Schomaker, J. M.; Borhan, B.

 

EJOC

 

 

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J. Org. Chem. 2004, 69, 9299-9302

 

Direct Oxidative Cleavage of alpha- and beta- Dicarbonyls and alpha-Hydroxyketones to Diesters with KHSO5

Yan, J.; Travis, B. R.; Borhan, B.

 

EJOC

 

 

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J. Am. Chem. Soc. 2004 126, 13600-13601

 

Synthesis of Diastereomerically and Enantiomerically Pure 2,3-Disubstituted Tetrahydrofurans Using a Sulfoxonium Ylide

Schomaker, J. M.; Pulgam, V. R.; Borhan, B.

 

EJOC

 

 

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Org. Biomol. Chem. 2004, 2, 621-624

 

Total Synthesis of (+)-Tanikolide via Oxidative Lactonization

Schomaker, J. M.; Borhan, B.

 

EJOC

 

 

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Org. Lett.. 2003, 5, 3089-3092

 

Direct Lactonization of Alkenols via Osmium Tetroxide-Mediated Oxidative Cleavage

Schomaker, J. M.; Travis, B. R.; Borhan, B.

 

EJOC

 

 

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Tet. Lett.. 2003, 44, 5547-5551

 

Regiochemical Control in Intramolecular Cyclization of 2,3-Epoxysulfides Mediated by Solvent Effects

Sivakumar, M.; Borhan, B.

 

EJOC

 

 

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Org. Lett. 2003, 5, 1031-1034

 

Facile Oxidation of Aldehydes to Acids and Esters with Oxone

Travis, B. R.; Sivakumar, M.; Hollist, G. O.; Borhan, B.

 

EJOC

 

 

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Eur. J. Org. Chem. 2002, 20, 3429-3434

 

Preparation of Purified KHSO5.H2O and nBu4NHSO5 from Oxone by Simple and Efficient Methods

Travis, B. R.; Ciaramitaro, B. P.; Borhan, B.

 

EJOC

 

 

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Org. Lett. 2002, 4, 3423-3426

 

Absolute Determination of Chiral Carboxylic Acids

Yang, Q.; Olmsted, C.; Borhan, B.

 

EJOC

 

 

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Tet. Lett. 2002, 43, 3867-3869

 

Synthesis of C15,C14'-Ring Locked all-trans-beta-Carotene

Reddy, P. V.; Borhan, B.

 

EJOC

 

 

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J. Am. Chem. Soc. 2002, 124, 3824-3825

 

Osmium Tetroxide-Promoted Catalytic Oxidative Cleavage of Olefins: An Organometallic Ozonolysis

Travis, B. R.; Narayan, R. S.; Borhan, B.

 

EJOC

 

 

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J. Labelled Comp. Radiopharm. 2002, 45, 79-89

 

Synthesis of all-trans-[10'-H-3]-8'-apo-beta-carotenoic acid

Reddy, P. V.; Rabago-Smith, M.; Borhan, B.

 

EJOC

 

 

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Tet. Lett. 2001 42, 7741-7745

 

Oxidative Cyclization of 1,4-Dienes to Yield 2,3,5-Trisubstituted Tetrahydrofuran-diols

Travis, B. R; Borhan, B.

 

EJOC

 

 

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Org. Lett. 2001, 3, 2489-2492

 

Regiochemical Control in Intramolecular Cyclization of Methylene-Interrupted Epoxydiols

NArayan, R. S.; Sivakumar, M.; Bouhlel, E.; Borhan, B.

 

EJOC

 

 

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Tet. Lett. 2001, 42, 619-621

 

Synthesis of Isomeric 1,4-[C-13](2)-Labeled 2-Ethoxycarbonyl-1,4-Diphenylbutadienes

Crist, R. M.; Reddy, P. V.; Borhan, B.

 

EJOC